Standard Article

Iridium, [N-[(1R,2R)-2-(amino-κN)cyclohexyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl]-, stereoisomer; Iridium, [N-[(1R,2R)-2-(amino-κN)cyclohexyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl]-; Iridium, [N-[(1S,2S)-2-(amino-κN)cyclohexyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl]-, stereoisomer

  1. Takao Ikariya

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn01597

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Ikariya, T. 2013. Iridium, [N-[(1R,2R)-2-(amino-κN)cyclohexyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl]-, stereoisomer; Iridium, [N-[(1R,2R)-2-(amino-κN)cyclohexyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl]-; Iridium, [N-[(1S,2S)-2-(amino-κN)cyclohexyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl]-, stereoisomer. e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. Tokyo Institute of Technology, Tokyo, Japan

Publication History

  1. Published Online: 16 SEP 2013

Featured Compounds

VIEW

  1. 1 - 36
Compound Information
Drug synonym:Not Available
Molecular Weight:796.698
Molecular Formula:C20H30Cl4Ir2
SMILES:Cl[Ir]Cl.Cl[Ir]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]1[C](C)[C](C)[C](C)[C]1C
InChI:1S/2C10H20.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*6-10H,1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChIKey:LPFQDSLPQTYADR-UHFFFAOYSA-J
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:101.19
Molecular Formula:C6H15N
SMILES:CCN(CC)CC
InChI:1S/C6H15N/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChIKey:ZMANZCXQSJIPKH-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:methylene chloride, methylene dichloride
Molecular Weight:84.933
Molecular Formula:CH2Cl2
SMILES:ClCCl
InChI:1S/CH2Cl2/c2-1-3/h1H2
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:178.2277
Molecular Formula:C11H14O2
SMILES:OC[C@H]1C[C@@H](O)c2ccccc2C1
InChI:1S/C11H14O2/c12-7-8-5-9-3-1-2-4-10(9)11(13)6-8/h1-4,8,11-13H,5-7H2/t8-,11-/m1/s1
InChIKey:HORBZNNRSXNJKD-LDYMZIIASA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:178.2277
Molecular Formula:C11H14O2
SMILES:OC[C@@H]1C[C@H](O)c2ccccc2C1
InChI:1S/C11H14O2/c12-7-8-5-9-3-1-2-4-10(9)11(13)6-8/h1-4,8,11-13H,5-7H2/t8-,11-/m0/s1
InChIKey:HORBZNNRSXNJKD-KWQFWETISA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:176.2118
Molecular Formula:C11H12O2
SMILES:OC[C@@H]1CC(=O)c2ccccc2C1
InChI:1S/C11H12O2/c12-7-8-5-9-3-1-2-4-10(9)11(13)6-8/h1-4,8,12H,5-7H2/t8-/m0/s1
InChIKey:CREVFIPIRJCEIY-QMMMGPOBSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:599.75
Molecular Formula:C31H34N2O2RuS
SMILES:CC(C)c1ccc(C)cc1.Cc1ccc(cc1)S(=O)(=O)N1[Ru]N[C@@H]([C@H]1c1ccccc1)c1ccccc1
InChI:1S/C21H20N2O2S.C10H14.Ru.4H/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;;;;/h2-15,20-22H,1H3;4-8H,1-3H3;;;;;/q-2;;+2;;;;/t20-,21-;;;;;;/m1....../s1
InChIKey:CPZIADVWRUNNBT-LGPFPQHZSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:58.0791
Molecular Formula:C3H6O
SMILES:CC(C)=O
InChI:1S/C3H6O/c1-3(2)4/h1-2H3
InChIKey:CSCPPACGZOOCGX-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:252.3062
Molecular Formula:C14H20O4
SMILES:CC1(C)O[C@H]2[C@@H](O1)[C@H](O)[C@@H]1[C@H]3C[C@H](C=C3)[C@@H]1[C@@H]2O
InChI:1S/C14H20O4/c1-14(2)17-12-10(15)8-6-3-4-7(5-6)9(8)11(16)13(12)18-14/h3-4,6-13,15-16H,5H2,1-2H3/t6-,7+,8-,9+,10-,11+,12+,13-
InChIKey:UCRAJZOMPJEEHD-RKPOYUIDSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:250.2903
Molecular Formula:C14H18O4
SMILES:CC1(C)O[C@@H]2[C@H](O1)C(=O)[C@H]1[C@@H]3C[C@@H](C=C3)[C@H]1[C@H]2O
InChI:1S/C14H18O4/c1-14(2)17-12-10(15)8-6-3-4-7(5-6)9(8)11(16)13(12)18-14/h3-4,6-10,12-13,15H,5H2,1-2H3/t6-,7+,8-,9+,10-,12+,13-/m1/s1
InChIKey:WCRWHUOIGFAUSQ-XEVMNIDFSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:691.904
Molecular Formula:C31H35IrN2O2S
SMILES:C[C]1[C](C)[C](C)[C](C)[C]1C.Cc1ccc(cc1)S(=O)(=O)N1[Ir]N[C@@H]([C@H]1c1ccccc1)c1ccccc1
InChI:1S/C21H20N2O2S.C10H20.Ir/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-6-7(2)9(4)10(5)8(6)3;/h2-15,20-22H,1H3;6-10H,1-5H3;/q-2;;+2/t20-,21-;;/m1../s1
InChIKey:QCIYTWZBKARJOW-OXIQQVKJSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:112.212
Molecular Formula:C4H9KO
SMILES:[K+].CC(C)(C)[O-]
InChI:1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChIKey:LPNYRYFBWFDTMA-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:98.143
Molecular Formula:C6H10O
SMILES:O=C1CCCCC1
InChI:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:310.3869
Molecular Formula:C20H22O3
SMILES:COc1ccc(CC2C[C@@H](C=C)[C@H]3C2C(=O)C=CC3=C)cc1O
InChI:1S/C20H22O3/c1-4-14-11-15(20-16(21)7-5-12(2)19(14)20)9-13-6-8-18(23-3)17(22)10-13/h4-8,10,14-15,19-20,22H,1-2,9,11H2,3H3/t14-,15?,19+,20?/m1/s1
InChIKey:ODHHTIYRUDURPW-QBVIUOPJSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:dl‐1‐phenylethanol, Î±â€methylbenzyl alcohol
Molecular Weight:122.1644
Molecular Formula:C8H10O
SMILES:CC(O)C1=CC=CC=C1
InChI:1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3
InChIKey:WAPNOHKVXSQRPX-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:122.1644
Molecular Formula:C8H10O
SMILES:C[C@@H](O)C1=CC=CC=C1
InChI:1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-/m1/s1
InChIKey:WAPNOHKVXSQRPX-SSDOTTSWSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:1‐Phenylethanone, phenyl methyl ketone
Molecular Weight:120.1485
Molecular Formula:C8H8O
SMILES:CC(=O)C1=CC=CC=C1
InChI:1S/C8H8O/c1-7(9)8-5-3-2-4-6-8/h2-6H,1H3
InChIKey:KWOLFJPFCHCOCG-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:615.808
Molecular Formula:C25H31IrN2O2S
SMILES:C[C]1[C](C)[C](C)[C](C)[C]1C.CS(=O)(=O)N1[Ir]N[C@H]([C@@H]1c1ccccc1)c1ccccc1
InChI:1S/C15H16N2O2S.C10H20.Ir/c1-20(18,19)17-15(13-10-6-3-7-11-13)14(16)12-8-4-2-5-9-12;1-6-7(2)9(4)10(5)8(6)3;/h2-11,14-16H,1H3;6-10H,1-5H3;/q-2;;+2/t14-,15-;;/m0../s1
InChIKey:UCTZYGIGFZDEHM-WVFPUEBHSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:72.1057
Molecular Formula:C4H8O
SMILES:C1CCOC1
InChI:1S/C4H8O/c1-2-4-5-3-1/h1-4H2
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:630.263
Molecular Formula:C23H34ClIrN2O2S
SMILES:C[C]1[C](C)[C](C)[C](C)[C]1C.Cc1ccc(cc1)S(=O)(=O)N([Ir]Cl)[C@H]1CCCC[C@@H]1N
InChI:1S/C13H19N2O2S.C10H20.ClH.Ir/c1-10-6-8-11(9-7-10)18(16,17)15-13-5-3-2-4-12(13)14;1-6-7(2)9(4)10(5)8(6)3;;/h6-9,12-13H,2-5,14H2,1H3;6-10H,1-5H3;1H;/q-1;;;+2/p-1/t12-,13-;;;/m0.../s1
InChIKey:WBQXMSSCDQUOMU-SQWZUNHGSA-M
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:209.2863
Molecular Formula:C15H15N
SMILES:C\C(=N\CC1=CC=CC=C1)C1=CC=CC=C1
InChI:1S/C15H15N/c1-13(15-10-6-3-7-11-15)16-12-14-8-4-2-5-9-14/h2-11H,12H2,1H3/b16-13-
InChIKey:JATCPLSBWDXCNE-SSZFMOIBSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:211.3022
Molecular Formula:C15H17N
SMILES:C[C@H](NCc1ccccc1)c1ccccc1
InChI:1S/C15H17N/c1-13(15-10-6-3-7-11-15)16-12-14-8-4-2-5-9-14/h2-11,13,16H,12H2,1H3/t13-/m0/s1
InChIKey:ZYZHMSJNPCYUTB-ZDUSSCGKSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:211.3022
Molecular Formula:C15H17N
SMILES:C[C@@H](NCC1=CC=CC=C1)C1=CC=CC=C1
InChI:1S/C15H17N/c1-13(15-10-6-3-7-11-15)16-12-14-8-4-2-5-9-14/h2-11,13,16H,12H2,1H3/t13-/m1/s1
InChIKey:ZYZHMSJNPCYUTB-CYBMUJFWSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:630.263
Molecular Formula:C23H34ClIrN2O2S
SMILES:C[C]1[C](C)[C](C)[C](C)[C]1C.[H]N([H])[C@]1([H])CCCC[C@@]1([H])N([Ir]Cl)S(=O)(=O)C1=CC=C(C)C=C1
InChI:1S/C13H19N2O2S.C10H20.ClH.Ir/c1-10-6-8-11(9-7-10)18(16,17)15-13-5-3-2-4-12(13)14;1-6-7(2)9(4)10(5)8(6)3;;/h6-9,12-13H,2-5,14H2,1H3;6-10H,1-5H3;1H;/q-1;;;+2/p-1/t12-,13-;;;/m1.../s1
InChIKey:WBQXMSSCDQUOMU-GPWCTTBFSA-M
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:343.62
Molecular Formula:AgF6Sb
SMILES:[Ag+].F[Sb-](F)(F)(F)(F)F
InChI:1S/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6
InChIKey:GSXFODUDOAXUBF-UHFFFAOYSA-H
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:isopropyl alcohol
Molecular Weight:60.095
Molecular Formula:C3H8O
SMILES:CC(C)O
InChI:1S/C3H8O/c1-3(2)4/h3-4H,1-2H3
InChIKey:KFZMGEQAYNKOFK-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:870.6
Molecular Formula:C25H36F6IrN3O2SSb
SMILES:CC#N.F[Sb-](F)(F)(F)(F)F.C[C]1[C](C)[C](C)[C](C)[C]1C.Cc1ccc(cc1)S(=O)(=O)N1[Ir+]N[C@H]2CCCC[C@H]12
InChI:1S/C13H18N2O2S.C10H20.C2H3N.6FH.Ir.Sb/c1-10-6-8-11(9-7-10)18(16,17)15-13-5-3-2-4-12(13)14;1-6-7(2)9(4)10(5)8(6)3;1-2-3;;;;;;;;/h6-9,12-14H,2-5H2,1H3;6-10H,1-5H3;1H3;6*1H;;/q-2;;;;;;;;;+3;+5/p-6/t12-,13-;;;;;;;;;;/m0........../s1
InChIKey:NVVLCKNNCIVJBG-UYYRLJAOSA-H
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:188.1465
Molecular Formula:C9H7F3O
SMILES:CC(=O)C1=CC(=CC=C1)C(F)(F)F
InChI:1S/C9H7F3O/c1-6(13)7-3-2-4-8(5-7)9(10,11)12/h2-5H,1H3
InChIKey:ABXGMGUHGLQMAW-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:190.1624
Molecular Formula:C9H9F3O
SMILES:C[C@@H](O)C1=CC(=CC=C1)C(F)(F)F
InChI:1S/C9H9F3O/c1-6(13)7-3-2-4-8(5-7)9(10,11)12/h2-6,13H,1H3/t6-/m1/s1
InChIKey:YNVXCOKNHXMBQC-ZCFIWIBFSA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:190.1624
Molecular Formula:C9H9F3O
SMILES:C[C@H](O)C1=CC(=CC=C1)C(F)(F)F
InChI:1S/C9H9F3O/c1-6(13)7-3-2-4-8(5-7)9(10,11)12/h2-6,13H,1H3/t6-/m0/s1
InChIKey:YNVXCOKNHXMBQC-LURJTMIESA-N
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound

VIEW

  1. 1 - 36