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Manganese(2+), bis(octahydro-1,4,7-trimethyl-1H-1,4,7-triazonine-κN1N4N7)tri-μ-oxodi-, hexafluorophosphate(1−) (1:2)

  1. Jitendra D. Belani

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn01603

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Belani, J. D. 2013. Manganese(2+), bis(octahydro-1,4,7-trimethyl-1H-1,4,7-triazonine-κN1N4N7)tri-μ-oxodi-, hexafluorophosphate(1−) (1:2). e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. Jefferson School of Pharmacy, Philadelphia, PA, USA

Publication History

  1. Published Online: 16 SEP 2013

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Abstract

Alternate Names: manganese(2+), bis(octahydro-1,4,7-trimethyl-1H-1,4,7-triazonine-N1,N4,N7)tri-μ-oxodi-, bis[hexafluorophosphate(1−)]; manganese(2+), bis(octahydro-1,4,7-trimethyl-1H-1,4,7-triazonine-κN1N4N7)tri-μ-oxodi-, bis[hexafluorophosphate(1−)] (9CI); 1H-1,4,7-triazonine, manganese(2+) deriv.; 1H-1,4,7-Triazonine, octahydro-1,4,7-trimethyl-, manganese complex; tris-μ-oxobis[(1,4,7-trimethyl-1,4,7-triazacyclononane)manganese(IV)] hexafluorophosphate.

Preparative Methods: The manganese(IV) complex salt 1 is prepared by heating MnCl2·4H2O (1 equiv), 1,4,7-trimethyl-1,4,7-triazacyclonane (TMACN, L, 1 equiv), and potassium hexafluorophosphate in ethanol/water (2:1) at 50 °C. The resultant reaction mixture is treated with basic solution of H2O2 (1.5 equiv) at 0 °C, and subsequently acidified, concentrated, redissolved in acetonitrile and precipitated using diethyl ether to give red–orange microcrystals (81%) of [L2Mn(μ-O)3MnL](PF6)2, 1.1 Alternatively, 1 can be prepared by counterion exchange of[L2MnIII2(μ-O)(μ-CH3CO2)2] (ClO4)2·H2O with NaPF6.2

Solubility: soluble in acetone, acetonitrile, nitromethane, and methanol; insoluble in ether.

Featured Compounds

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  1. 1 - 72
Compound Information
Molecular Weight:104.1491
Molecular Formula:C8H8
InChIKey:PPBRXRYQALVLMV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:Not Available
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Compound Information
Molecular Weight:790.3689
Molecular Formula:C18H42F12Mn2N6O3P2
InChIKey:VBHAVHBRSBJJFL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:34.0147
Molecular Formula:H2O2
InChIKey:MHAJPDPJQMAIIY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:32.0419
Molecular Formula:CH4O
InChIKey:OKKJLVBELUTLKV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:148.1586
Molecular Formula:C9H8O2
InChIKey:IRQWEODKXLDORP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:164.158
Molecular Formula:C9H8O3
InChIKey:VCZAQQDKQNHPDZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:WVDDGKGOMKODPV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:HUMNYLRZRPPJDN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:58.0791
Molecular Formula:C3H6O
InChIKey:CSCPPACGZOOCGX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:90.121
Molecular Formula:C4H10O2
InChIKey:CIHOLLKRGTVIJN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:138.1638
Molecular Formula:C8H10O2
InChIKey:MSHFRERJPWKJFX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:136.1479
Molecular Formula:C8H8O2
InChIKey:ZRSNZINYAWTAHE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:153.1354
Molecular Formula:C7H7NO3
InChIKey:Not Available
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Compound Information
Molecular Weight:151.1195
Molecular Formula:C7H5NO3
InChIKey:BXRFQSNOROATLV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:98.1861
Molecular Formula:C7H14
InChIKey:UAEPNZWRGJTJPN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:114.1855
Molecular Formula:C7H14O
InChIKey:VTBOTOBFGSVRMA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:112.1696
Molecular Formula:C7H12O
InChIKey:LFSAPCRASZRSKS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:112.1696
Molecular Formula:C7H12O
InChIKey:UJBOOUHRTQVGRU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:112.1696
Molecular Formula:C7H12O
InChIKey:VGVHNLRUAMRIEW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:114.1855
Molecular Formula:C7H14O
InChIKey:NDVWOBYBJYUSMF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:114.1855
Molecular Formula:C7H14O
InChIKey:HTSABYAWKQAHBT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:114.1855
Molecular Formula:C7H14O
InChIKey:MQWCXKGKQLNYQG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:76.0514
Molecular Formula:C2H4O3
InChIKey:Not Available
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Compound Information
Molecular Weight:41.0519
Molecular Formula:C2H3N
InChIKey:WEVYAHXRMPXWCK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:262.2855
Molecular Formula:C18H15P
InChIKey:RIOQSEWOXXDEQQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:86.1754
Molecular Formula:C6H14
InChIKey:VLKZOEOYAKHREP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:102.1748
Molecular Formula:C6H14O
InChIKey:ZOCHHNOQQHDWHG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:PFCHFHIRKBAQGU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:60.052
Molecular Formula:C2H4O2
InChIKey:QTBSBXVTEAMEQO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:88.1482
Molecular Formula:C5H12O
InChIKey:AQIXEPGDORPWBJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:86.1323
Molecular Formula:C5H10O
InChIKey:FDPIMTJIUBPUKL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:88.1482
Molecular Formula:C5H12O
InChIKey:AMQJEAYHLZJPGS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:86.1323
Molecular Formula:C5H10O
InChIKey:HGBOYTHUEUWSSQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:102.1317
Molecular Formula:C5H10O2
InChIKey:NQPDZGIKBAWPEJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.1632
Molecular Formula:C8H10O3
InChIKey:KLIDCXVFHGNTTM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:153.1553
Molecular Formula:C8H9O3
InChIKey:KLIDCXVFHGNTTM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:18.0153
Molecular Formula:H2O
InChIKey:XLYOFNOQVPJJNP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:304.2946
Molecular Formula:C16H16O6
InChIKey:WASNBVDBYSQBPH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.229
Molecular Formula:C8H10OS
InChIKey:DQNSKXYRRRCKGH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:170.229
Molecular Formula:C8H10O2S
InChIKey:XSFFUNMJITWEEA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:186.228
Molecular Formula:C8H10O3S
InChIKey:KAZUCVUGWMQGMC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:160.2124
Molecular Formula:C11H12O
InChIKey:Not Available
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Compound Information
Molecular Weight:194.2271
Molecular Formula:C11H14O3
InChIKey:XPERSQUJKVIRHQ-NXEZZACHSA-N
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Compound Information
Molecular Weight:194.2271
Molecular Formula:C11H14O3
InChIKey:XPERSQUJKVIRHQ-UWVGGRQHSA-N
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Compound Information
Molecular Weight:193.1992
Molecular Formula:C10H11NO3
InChIKey:VKDFZMMOLPIWQQ-SECBINFHSA-N
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Compound Information
Molecular Weight:3875.02
Molecular Formula:C36H84Mn4N12O46SiW12
InChIKey:AEDBQSNFPGAHSA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:2878.17
Molecular Formula:H4O40SiW12
InChIKey:CGFYHILWFSGVJS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:46.0684
Molecular Formula:C2H6O
InChIKey:LFQSCWFLJHTTHZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:102.1748
Molecular Formula:C6H14O
InChIKey:ZSIAUFGUXNUGDI-UHFFFAOYSA-N
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Compound Information
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:JARKCYVAAOWBJS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:116.1583
Molecular Formula:C6H12O2
InChIKey:Not Available
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Compound Information
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:SAOXPNBHKSWHGW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:116.1583
Molecular Formula:C6H12O2
InChIKey:YSDUPQNXIOJZPX-CRCLSJGQSA-N
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Compound Information
Molecular Weight:116.1583
Molecular Formula:C6H12O2
InChIKey:YSDUPQNXIOJZPX-WHFBIAKZSA-N
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Compound Information
Molecular Weight:98.143
Molecular Formula:C6H10O
InChIKey:SHOJXDKTYKFBRD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:184.1224
Molecular Formula:C6H9NaO5
InChIKey:QWIAPYXILFQNSC-KQRLMAEXSA-M
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Compound Information
Molecular Weight:192.2112
Molecular Formula:C11H12O3
InChIKey:NXPVXGMVVNYCGZ-VMPITWQZSA-N
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Compound Information
Molecular Weight:147.1308
Molecular Formula:C8H5NO2
InChIKey:XKJCHHZQLQNZHY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:263.2906
Molecular Formula:C17H13NO2
InChIKey:UGZKIJQHQMDTRO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:671.702
Molecular Formula:C16H24Cl2Ir2
InChIKey:ZFOUDQNHNLDNLD-MIXQCLKLSA-L
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Compound Information
Molecular Weight:538.6146
Molecular Formula:C37H31O2P
InChIKey:FZTQBGFXKAKMMZ-CLJLJLNGSA-N
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Compound Information
Molecular Weight:139.1982
Molecular Formula:C7H13N3
InChIKey:FVKFHMNJTHKMRX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:279.29
Molecular Formula:C17H13NO3
InChIKey:MHQQGQNGVWOOMW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:177.33
Molecular Formula:Cl2Pd
InChIKey:PIBWKRNGBLPSSY-UHFFFAOYSA-L
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Compound Information
Molecular Weight:98.999
Molecular Formula:ClCu
InChIKey:OXBLHERUFWYNTN-UHFFFAOYSA-M
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Compound Information
Molecular Weight:73.0938
Molecular Formula:C3H7NO
InChIKey:ZMXDDKWLCZADIW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:295.2894
Molecular Formula:C17H13NO4
InChIKey:VXNFNYYAZGURGL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:163.387
Molecular Formula:C2HCl3O2
InChIKey:YNJBWRMUSHSURL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:165.1891
Molecular Formula:C9H11NO2
InChIKey:UJOYFRCOTPUKAK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:32.0452
Molecular Formula:H4N2
InChIKey:OAKJQQAXSVQMHS-UHFFFAOYSA-N
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