Standard Article

Tetrabutylammonium Perchlorate

  1. Katherine L. Hervert

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn01604

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Hervert, K. L. 2013. Tetrabutylammonium Perchlorate. e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. Ohio Wesleyan University, Delaware, OH, USA

Publication History

  1. Published Online: 16 SEP 2013

Chemistry Terms

Choose one or more boxes to highlight terms.

Abstract

(supporting electrolyte, electrochemical reductions, electrogenerated acids, electrochemical polymerization catalyst, phase-transfer catalyst)

Alternate Name: TBAP, TBAPC.

Physical Data: 211–215 °C, d 1.07 g cm−3.

Solubility: soluble in ethanol, methanol, and very slightly soluble in water and 0.1 g mL−1 in acetonitrile.

Form Supplied in: white powder; readily available in anhydrous form 98–100%.

Analysis of Reagent Purity: ion exchange titration 98.0%.

Preparative Method: commercially available. Tetrabutylammonium perchlorate has been synthesized from precipitated silver halides and drying agents.1-3 Tetrabutylammonium perchlorate can also be obtained from the addition of sodium perchlorate to a hot ethanol solution of tetra-n-butylammonium bromide and recrystallized from aqueous ethanol.4 An aqueous solution of KClO4 was added to an aqueous solution of tetra-n-butylammonium sulfate. The precipitate was filtered and washed with H2O and dried over P2O5 to give the white solid in 48%.5

Purification: recrystallized from aqueous methanol, ethanol, ethyl acetate, or water and dried over P2O5.

Handling, Storage, and Precautions: heating may cause an explosion and should be kept away from combustible material and organic materials in a cool, dry, tightly closed container. May cause skin irritation. Strong oxidizer. Hygroscopic.

Featured Compounds

VIEW

  1. 1 - 60
Compound Information
Molecular Weight:341.914
Molecular Formula:C16H36ClNO4
InChIKey:KBLZDCFTQSIIOH-UHFFFAOYSA-M
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:340.053
Molecular Formula:C14H12Br2
InChIKey:GKESIQQTGWVOLH-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:180.2451
Molecular Formula:C14H12
InChIKey:PJANXHGTPQOBST-VAWYXSNFSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:73.0938
Molecular Formula:C3H7NO
InChIKey:ZMXDDKWLCZADIW-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:219.2796
Molecular Formula:C13H17NO2
InChIKey:SWJMYFGBQCCKMR-IGVUGNCQSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:108.642
Molecular Formula:C3H9ClSi
InChIKey:IJOOHPMOJXWVHK-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:140.567
Molecular Formula:C7H5ClO
InChIKey:PASDCCFISLVPSO-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:101.19
Molecular Formula:C6H15N
InChIKey:ZMANZCXQSJIPKH-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:94.497
Molecular Formula:C2H3ClO2
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:218.2469
Molecular Formula:C10H18O5
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:236.2637
Molecular Formula:C13H16O4
InChIKey:FZIZKCLZDZFXCI-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:206.2378
Molecular Formula:C12H14O3
InChIKey:VJGWOAKXLPMDGI-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:261.4621
Molecular Formula:C16H36FN
InChIKey:FPGGTKZVZWFYPV-UHFFFAOYSA-M
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:389.281
Molecular Formula:C17H25BrO5
InChIKey:NRIHCHSTXAOPAQ-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:387.266
Molecular Formula:C17H23BrO5
InChIKey:NSOLJYOMRQNWRM-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:58.0791
Molecular Formula:C3H6O
InChIKey:CSCPPACGZOOCGX-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:FXLOVSHXALFLKQ-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:104.578
Molecular Formula:C5H9Cl
InChIKey:JKXQKGNGJVZKFA-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:190.2814
Molecular Formula:C13H18O
InChIKey:BPDWBUQPEPDGOH-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:190.2814
Molecular Formula:C13H18O
InChIKey:LLTZXXNHVAUPDN-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:179.2004
Molecular Formula:C6H18N3OP
InChIKey:GNOIPBMMFNIUFM-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:134.1751
Molecular Formula:C9H10O
InChIKey:YGCZTXZTJXYWCO-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:184.2338
Molecular Formula:C13H12O
InChIKey:URGUYLDLUKQNJQ-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:316.393
Molecular Formula:C22H20O2
InChIKey:GEXIXPPHYYWGDZ-MQVYOEOJSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:316.393
Molecular Formula:C22H20O2
InChIKey:GEXIXPPHYYWGDZ-LMVYJXDASA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:246.348
Molecular Formula:C15H22N2O
InChIKey:SKHPYKHVYFTIOI-TZMCWYRMSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:84.933
Molecular Formula:CH2Cl2
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:662.834
Molecular Formula:C41H42O6S
InChIKey:IUEGLUASEAHJSP-NEJZJLHVSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:252.3923
Molecular Formula:C16H28O2
InChIKey:VLDWTWNFUSHIMR-DHGKCCLASA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:775.0231
Molecular Formula:C50H62O7
InChIKey:AWVCYSILTQQRDZ-JEECLSMCSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:775.0231
Molecular Formula:C50H62O7
InChIKey:AWVCYSILTQQRDZ-PZFXEFEHSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:41.0519
Molecular Formula:C2H3N
InChIKey:WEVYAHXRMPXWCK-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:114.1424
Molecular Formula:C6H10O2
InChIKey:ZMIARSDHSWUVIA-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:66.1011
Molecular Formula:C5H6
InChIKey:ZSWFCLXCOIISFI-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:180.2435
Molecular Formula:C11H16O2
InChIKey:OCYNXDSJBIOZHM-AEJSXWLSSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:106.392
Molecular Formula:ClLiO4
InChIKey:MHCFAGZWMAWTNR-UHFFFAOYSA-M
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:152.1904
Molecular Formula:C9H12O2
InChIKey:HEVMDQBCAHEHDY-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:218.2915
Molecular Formula:C14H18O2
InChIKey:LRFLORXTZQEIMB-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:395.599
Molecular Formula:C22H37NO3S
InChIKey:RIPMZMSSKCHDMB-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:297.476
Molecular Formula:C18H35NO2
InChIKey:JWVRHSKLWBXCIF-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:123.1094
Molecular Formula:C6H5NO2
InChIKey:LQNUZADURLCDLV-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:107.11
Molecular Formula:C6H5NO
InChIKey:NLRKCXQQSUWLCH-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:122.1213
Molecular Formula:C7H6O2
InChIKey:WPYMKLBDIGXBTP-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:168.021
Molecular Formula:C7H9BO2S
InChIKey:IVUHTLFKBDDICS-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:140.203
Molecular Formula:C7H8OS
InChIKey:QASBCTGZKABPKX-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:542.003
Molecular Formula:C26H24ClN3O6S
InChIKey:LRPWIFIWTGEIAB-XCVFGXLCSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:278.775
Molecular Formula:C19H15Cl
InChIKey:JBWKIWSBJXDJDT-UHFFFAOYSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:784.318
Molecular Formula:C45H38ClN3O6S
InChIKey:AGEZKDCIZITKGF-ILGQZQAUSA-N
View compound in article | Full details | Search for this compound
Compound Information
Molecular Weight:121.1796
Molecular Formula:C8H11N
InChIKey:Not Available
View compound in article | Full details | Search for this compound

VIEW

  1. 1 - 60