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Rhenium, [2-(mercapto-κS)benzenemethanethiolato(2–)-κS]methyloxo(triphenylphosphine)

  1. David J. Meyers

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn01613

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Meyers, D. J. 2013. Rhenium, [2-(mercapto-κS)benzenemethanethiolato(2–)-κS]methyloxo(triphenylphosphine). e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. Johns Hopkins University School of Medicine, Baltimore, MD, USA

Publication History

  1. Published Online: 16 SEP 2013

Chemistry Terms

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Abstract

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[354565-70-1] & [222734-85-2] C26H24OPReS2 (MW 633.78)

(reagent used in oxygen-atom transfer (OAT) reactions)

Alternate Names: MeReO(mtp)PPh3, where mtpH2 is 2-(mercaptomethyl)thiophenol.

Physical Data: N/A. Characterization Data: 1H and 13C NMR, elemental analysis, X-ray structure, and molar absorptivity.

Solubility: benzene, toluene, tetrahydrofuran (must be freshly distilled to avoid peroxides destroying the catalyst), chloroform, and acetonitrile.1

Preparative Method: prepared by the exposure of rhenium, bis[µ-[2-(mercapto-κS)benzenemethanethiolato(2–)-κS: κS]dimethyldioxodi-, (222734-84-1, trivial name {MeReO(mtp)}2), with triphenylphosphine.1

Featured Compounds

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  1. 1 - 35
Compound Information
Molecular Weight:109.1259
Molecular Formula:C6H7NO
InChIKey:CFZKDDTWZYUZKS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:262.2855
Molecular Formula:C18H15P
InChIKey:RIOQSEWOXXDEQQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:93.1265
Molecular Formula:C6H7N
InChIKey:BSKHPKMHTQYZBB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:278.2849
Molecular Formula:C18H15OP
InChIKey:FIQMHBFVRAXMOP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:633.779
Molecular Formula:C26H24OPReS2
InChIKey:MYNRNTFXLDIXRX-UHFFFAOYSA-L
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Compound Information
Molecular Weight:322.368
Molecular Formula:C16H36BrN
InChIKey:Not Available
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Compound Information
Molecular Weight:78.1118
Molecular Formula:C6H6
InChIKey:UHOVQNZJYSORNB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:123.1525
Molecular Formula:C7H9NO
InChIKey:LIDGFHXPUOJZMK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:107.1531
Molecular Formula:C7H9N
InChIKey:OISVCGZHLKNMSJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:YXFVVABEGXRONW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.1234
Molecular Formula:C6H6N2O3
InChIKey:FTTIAVRPJGCXAC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:138.124
Molecular Formula:C6H6N2O2
InChIKey:HWPIDHRDNNZJSY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:111.0987
Molecular Formula:C5H5NO2
InChIKey:JVHZMYAXZUIZKS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:95.0993
Molecular Formula:C5H5NO
InChIKey:UBQKCCHYAOITMY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:111.0987
Molecular Formula:C5H5NO2
InChIKey:YMEZKRMAPQIBQH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:95.0993
Molecular Formula:C5H5NO
InChIKey:Not Available
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Compound Information
Molecular Weight:125.1253
Molecular Formula:C6H7NO2
InChIKey:LQYJAVWWKTWWKN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:109.1259
Molecular Formula:C6H7NO
InChIKey:MVQVNTPHUGQQHK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:138.124
Molecular Formula:C6H6N2O2
InChIKey:USSFUVKEHXDAPM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:122.1246
Molecular Formula:C6H6N2O
InChIKey:DFPAKSUCGFBDDF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:139.1088
Molecular Formula:C6H5NO3
InChIKey:FJCFFCXMEXZEIM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:123.1094
Molecular Formula:C6H5NO2
InChIKey:PVNIIMVLHYAWGP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:18.0153
Molecular Formula:H2O
InChIKey:XLYOFNOQVPJJNP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:129.544
Molecular Formula:C5H4ClNO
InChIKey:DPJVRASYWYOFSJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:113.545
Molecular Formula:C5H4ClN
InChIKey:PVMNPAUTCMBOMO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:125.1253
Molecular Formula:C6H7NO2
InChIKey:BOFAIBPJCWFJFT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:109.1259
Molecular Formula:C6H7NO
InChIKey:XQABVLBGNWBWIV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:171.1953
Molecular Formula:C11H9NO
InChIKey:VZOPVKZLLGMDDG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:155.1959
Molecular Formula:C11H9N
InChIKey:JVZRCNQLWOELDU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:140.0969
Molecular Formula:C5H4N2O3
InChIKey:RXKNNAKAVAHBNK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:124.0975
Molecular Formula:C5H4N2O2
InChIKey:FEXIEMAAKBNTFK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:90.121
Molecular Formula:C4H10O2
InChIKey:CIHOLLKRGTVIJN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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