Standard Article

2-Hydroxy-5-methoxy-α,α-diphenyl-benzenemethanol

  1. Pengfei Wang

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn01627

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Wang, P. 2013. 2-Hydroxy-5-methoxy-α,α-diphenyl-benzenemethanol. e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. University of Alabama at Birmingham, AL, USA

Publication History

  1. Published Online: 16 SEP 2013

Chemistry Terms

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Abstract

(formation of acetals and ketals from carbonyls, oxidation of alcohols, ethers, and esters, carbonyl protecting group reagent)

Alternative Name:2-hydroxy-5-methoxy-α,α-diphenylbenzyl alcohol; 5-methoxy-α,α-diphenylsalicyl alcohol; MDPS.

Physical Data: mp 144 °C (decomp).

Solubility: soluble in CH2Cl2, CHCl3, THF, EtOAc, MeCN, toluene, DMF, and DMSO.

Form Supplied in: white solid; not available commercially.

Analysis of Reagent Purity: NMR.

Preparative Methods: by treatment of methyl 5-methoxysalicylate or 5-methoxysalicylic acid with either phenylmagnesium bromide or phenyllithium in THF or diethyl ether at room temperature.1

Purification: silica gel column chromatography.

Handling, Storage, and Precautions: the reagent is stable under ambient conditions and indoor lighting.

Featured Compounds

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  1. 1 - 25
Compound Information
Molecular Weight:306.3551
Molecular Formula:C20H18O3
InChIKey:GBLZWEKUXOKNBV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:172.202
Molecular Formula:C7H8O3S
InChIKey:JOXIMZWYDAKGHI-UHFFFAOYSA-N
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Compound Information
Molecular Weight:159.609
Molecular Formula:CuO4S
InChIKey:ARUVKPQLZAKDPS-UHFFFAOYSA-L
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Compound Information
Molecular Weight:78.1118
Molecular Formula:C6H6
InChIKey:UHOVQNZJYSORNB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:141.9445
Molecular Formula:O5P2
InChIKey:YWEUIGNSBFLMFL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:136.191
Molecular Formula:C9H12O
InChIKey:VAJVDSVGBWFCLW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:422.5149
Molecular Formula:C29H26O3
InChIKey:RFYGYSXYZKYKRH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:290.3557
Molecular Formula:C20H18O2
InChIKey:MAGZAGNAQMEVME-UHFFFAOYSA-N
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Compound Information
Molecular Weight:98.078
Molecular Formula:H2O4S
InChIKey:QAOWNCQODCNURD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:150.077
Molecular Formula:CHF3O3S
InChIKey:ITMCEJHCFYSIIV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:180.2435
Molecular Formula:C11H16O2
InChIKey:UOACSUDCGMMDFW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:178.2277
Molecular Formula:C11H14O2
InChIKey:PCBSXBYCASFXTM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:662.7689
Molecular Formula:C44H38O6
InChIKey:DNMQMSVNNMKVTA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:226.3135
Molecular Formula:C16H18O
InChIKey:UJEBVGCFOMTYGH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:394.4618
Molecular Formula:C27H22O3
InChIKey:LQYLWMAVXHBSNM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:180.2435
Molecular Formula:C11H16O2
InChIKey:TYROJDFHUXSBHC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:466.5675
Molecular Formula:C31H30O4
InChIKey:CHALTTRFCKKILZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:178.2277
Molecular Formula:C11H14O2
InChIKey:JRJGKUTZNBZHNK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:114.1424
Molecular Formula:C6H10O2
InChIKey:PAPBSGBWRJIAAV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:432.5082
Molecular Formula:C27H28O5
InChIKey:ICSOHOCOGRVGQV-UHFFFAOYSA-N
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