12. Spectroscopic Studies and Quantum-Chemical Calculations of Short-lived Germylenes, Stannylenes and Plumbylenes

  1. Zvi Rappoport
  1. Sergey E. Boganov,
  2. Mikhail P. Egorov,
  3. Valery I. Faustov and
  4. Oleg M. Nefedov

Published Online: 5 FEB 2003

DOI: 10.1002/0470857188.ch12

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

How to Cite

Boganov, S. E., Egorov, M. P., Faustov, V. I. and Nefedov, O. M. (2002) Spectroscopic Studies and Quantum-Chemical Calculations of Short-lived Germylenes, Stannylenes and Plumbylenes, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2 (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857188.ch12

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, Leninsky prospect, 47, 119991 Moscow, Russian Federation. Fax: 7–095-1356390

Publication History

  1. Published Online: 5 FEB 2003
  2. Published Print: 26 NOV 2002

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471497387

Online ISBN: 9780470857182

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Summary

This chapter contains sections titled:

  • List of Abbreviations

  • Introduction

  • Electronic Transitions in Triatomic and Tetraatomic Germylenes, Stannylenes and Plumbylenes

    • Prototype EH2 Molecules

    • EHal2 Molecules

    • EHHal Molecules

    • Comparison of the Molecular Constants of the Triatomic Carbene Analogs

    • Intrinsic Defects in Solid Silicon and Germanium Dioxides

    • Tetraatomic Carbene Analogs: Germylidene and Silylidene

  • Electronic Spectra of Polyatomic Germylenes, Stannylenes and Plumbylenes

    • Detection and Identification

    • Complications

    • Nature of Electronic Transitions in Polyatomic Germylenes, Stannylenes and Plumbylenes

    • Effects of Substituents on the Position of the Electronic Transition Band

    • Effect of the Nature of the Element E in R2E Species on the Position of Their Electronic Transition Band

  • Electronic Spectra of Intermolecular Complexes of Germylenes, Stannylenes and Plumbylenes with Lewis Bases

  • Vibrational Spectra of Germylenes, Stannylenes and Plumbylenes

    • Prototype EH2 Molecules

    • EHal2 Molecules

    • Mixed EXY Molecules

    • Some Conclusive Remarks on the Vibrational Spectra of the Triatomic Carbene Analogs

    • Polyatomic Germylenes, Stannylenes and Plumbylenes

  • Vibrational Spectra of Complexes of Germylenes, Stannylenes and Plumbylenes with Lewis Bases

  • Microwave Spectra of Germylenes. Structures of Short-lived Carbene Analogs

    • Rotational Transitions

    • The Ground State Geometries of Short-lived Carbene Analogs

  • Photoelectron Spectra, Ionization Energies, Electron Affinities and Redox Potentials of Germylenes, Stannylenes and Plumbylenes

    • Prototype EH2 Molecules

    • EHal2 Molecules

    • EHalHal′ Molecules

    • Acyclic Organyl and Aminogermylenes, -stannylenes and -plumbylenes

    • Cyclic Molecules

    • Electron Affinities

    • Electrochemistry

  • Quantum-chemical Calculations

    • Methods

    • Calculations of Electronic Transition Energies. Singlet–Triplet Energy Separations ΔEST

    • Reactions of R2E

      • Intrinsic Stability of R2E. Intramolecular Isomerizations

      • Dimerization

      • Insertions of CAs into H[BOND]H Bond and Their Reverse Reactions

      • Insertions into Other σ Bonds

      • Cycloadditions

      • Miscellaneous

    • Complexes with Lewis Bases

  • Conclusions

  • Acknowledgments

  • References