14. Unsaturated Three-Membered Rings of Heavier Group 14 Elements

  1. Zvi Rappoport
  1. Vladimir Ya. Lee and
  2. Akira Sekiguchi

Published Online: 5 FEB 2003

DOI: 10.1002/0470857188.ch14

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

How to Cite

Lee, V. Ya. and Sekiguchi, A. (2002) Unsaturated Three-Membered Rings of Heavier Group 14 Elements, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2 (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857188.ch14

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. Fax: (+81)-298-53-4314

Publication History

  1. Published Online: 5 FEB 2003
  2. Published Print: 26 NOV 2002

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471497387

Online ISBN: 9780470857182

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Summary

This chapter contains sections titled:

  • Introduction

  • Cyclotrimetallenes—Unsaturated Three-membered Rings of Heavier Group 14 Elements

    • Cyclotrisilenes

    • Cyclotrigermenes

    • Cyclotristannene

    • ‘Mixed’ Cyclotrimetallenes

    • Reactivity of Cyclotrimetallenes

      • Addition Reactions

        • Reactions with CCl4

      • Cycloaddition Reactions

        • Reactions with Phenylacetylene

        • Reactions with Aldehydes and Ketones

      • [4+2] Cycloaddition Reactions

        • Reactions with 1,3-dienes

    • Oxidation of Cyclotrigermenes—Formation of the ‘free’ Germyl Cation

  • Epilogue and Outlook

  • Acknowledgment

  • References