16. Hypervalent Compounds of Organic Germanium, Tin and Lead Derivatives

  1. Zvi Rappoport
  1. Yuri I. Baukov1 and
  2. Stanislav N. Tandura2

Published Online: 5 FEB 2003

DOI: 10.1002/0470857188.ch16

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

How to Cite

Baukov, Y. I. and Tandura, S. N. (2002) Hypervalent Compounds of Organic Germanium, Tin and Lead Derivatives, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2 (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857188.ch16

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. 1

    Department of General and Bioorganic Chemistry, Russian State Medical University, 1 Ostrovityanov St, 117997 Moscow, Russia. Fax: +7 (095) 4344787

  2. 2

    N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russia. Fax: +7 (095) 1355328

Publication History

  1. Published Online: 5 FEB 2003
  2. Published Print: 26 NOV 2002

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471497387

Online ISBN: 9780470857182

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Summary

This chapter contains sections titled:

  • List of Abbreviations

  • Introduction and Outline

    • Introduction

    • Outline

  • Self-associates

    • N [RIGHTWARDS ARROW] M Coordination

    • O [RIGHTWARDS ARROW] M Coordination

    • Hal [RIGHTWARDS ARROW] M Coordination

    • Other X [RIGHTWARDS ARROW] M Coordination

  • Pentacoordinate Anionic Compounds

    • Intermolecular Complexes

      • Tetraorganotin and Tetra- and Triorganogermanium Derivatives

      • Triorganostannates

        • Synthesis

        • Crystal Structures

        • NMR Spectroscopy

      • Bridged Triorganostannates

      • Diorganostannates

      • Organotetrahalostannates and Related Species

      • Zwitterionic Stannates

    • Intramolecular Complexes

      • Monocyclic Derivatives

        • Tin

        • Lead

      • Spirocyclic Derivatives

        • Germanium

        • Tin

      • Zwitterionic Spirogermanates

  • Pentacoordinate Intermolecular Neutral Compounds

    • Germanium

    • Tin

      • N [RIGHTWARDS ARROW] Sn Coordination

      • O [RIGHTWARDS ARROW] Sn Coordination

      • P [RIGHTWARDS ARROW] Sn Coordination

    • Lead

  • Pentacoordinate Intramolecular Neutral Germanium Compounds

    • Monocyclic Complexes

      • Derivatives with Bidentate C,O-chelating Ligands

        • Compounds with 8-(methoxynaphthyl) Ligand

        • β-germyl-substituted Derivatives of Carboxylic Acids and Ketones

        • Amide-type (O[BOND]Ge) Compounds

          • Crystallographic Data

          • Dynamic 1- H NMR Spectroscopy

      • Derivatives with Other Bidentate Chelating Ligands

    • Bicyclic Complexes. Germocanes and Their Analogues

    • Tricyclic Complexes

      • Germatranes and Their C-organo-substituted Derivatives

        • Synthesis and Reactivities

        • Structure and Physical Properties

      • Homogermatranes, Germatranones, Carbagermatranes, Thia- and Azagermatranes

  • Pentacoordinate Intramolecular Neutral Tin and Lead Compounds

    • Monocyclic Complexes

      • Derivatives with Bidentate C,N- and C,P-chelating Ligands

        • Tetraorgano Compounds

        • Triorganotin Hydrides

        • Triorgano Compounds

        • Diorgano and Monoorgano Compounds

      • Derivatives with Bidentate C,O-chelating Ligands and Related Compounds

        • Hydroxy, Alkoxy and Acyloxy Groups as Donor Centers

        • Carbonyl and Related Groups as Donor Centers

      • Monocyclic Derivatives with Other Bidentate Chelating Ligands

    • Bicyclic Complexes

      • Stannocanes

      • Bicyclic Analogues of Stannocanes

    • Tricyclic Complexes

      • Stannatranes and Their Analogues

        • Synthesis and Reactivity

        • Structure and Physical Properties

      • Other Tricyclic Derivatives

  • Pentacoordinate Cationic Compounds

    • Germanium Intramolecular Complexes

    • Tin and Lead Complexes

      • Intermolecular Complexes

      • Intramolecular Complexes

  • Hexacoordinate Anionic Compounds

    • Intermolecular Complexes

      • Germanium

      • Tin and Lead

    • Intramolecular Complexes

  • Hexacoordinate Neutral Compounds

    • Complexes with Intermolecular Coordination

      • Germanium

      • Tin

        • XR3Sn · D2 Systems

        • X2R2Sn · D2 Systems

          • Octahedral Complexes with cis-D (trans-R) Structure

          • Octahedral Complexes with all-trans Structure

        • X3RM · D2 Systems

        • X4M · D2 Systems

      • Lead

    • Chelate Complexes

      • One Multidentate Ligand

      • Two Multidentate Ligands

        • Four-membered Chelate Rings

        • Five-membered Chelate Rings (N [RIGHTWARDS ARROW] M)

        • Five-membered Chelate Rings (O [RIGHTWARDS ARROW] M)

        • Six-membered Chelate Rings

        • Miscellaneous

  • Hexacoordinate Cationic Tin Compounds

    • Intermolecular Complexes

    • Intramolecular Complexes

  • Acknowledgments

  • References