17. Transition Metal Complexes of Germanium, Tin and Lead

  1. Zvi Rappoport
  1. Hemant K. Sharma,
  2. Ionel Haiduc and
  3. Keith H. Pannell

Published Online: 5 FEB 2003

DOI: 10.1002/0470857188.ch17

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

How to Cite

Sharma, H. K., Haiduc, I. and Pannell, K. H. (2002) Transition Metal Complexes of Germanium, Tin and Lead, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2 (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857188.ch17

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968, USA. Fax: +915-747-5748

Publication History

  1. Published Online: 5 FEB 2003
  2. Published Print: 26 NOV 2002

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471497387

Online ISBN: 9780470857182

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Summary

This chapter contains sections titled:

  • Abbreviations

  • Introduction

  • Organogermanium Transition Metal Complexes

    • Synthesis of Transition Metal Germanium Single Bond

      • Synthesis from Transition Metal Anions and Germyl Halides

      • Synthesis from Transition Metal Halides and Germyl Anions

      • Anionic Germyl Metal Carbonyl Complexes

      • Oxidative Addition of Germyl Compounds to Metal Centers: Germyl Hydrides, Ge[BOND]H

      • Oxidative Addition of Germyl-germanes, -silanes and -halides

      • Insertion of Germylenes into Metal[BOND]Halogen, [BOND]Hydrogen and [BOND]Metal Bonds

      • Elimination Reactions Using Germyl Hydrides

      • Miscellaneous Reactions

      • Digermene Complexes

    • Synthesis of Bimetallic Bridging Germylene Complexes, LMGeR2ML

      • Complexes with a Metal Metal Bond

      • Complexes without a Metal Metal Bond

    • Synthesis of Transition Metal Germanium Double Bond Germylene Complexes

      • Base-free Metal Germylene Complexes

      • Cationic Germylene Complexes

      • Base-stabilized Germylene Complexes

    • Synthesis of Transition Metal Germanium Triple Bond Germylyne Complexes

    • The Reactivity of the Transition Metal Germanium Single Bond

      • Cleavage Reactions

      • Metal Digermyl, Germylsilyl and Germylstannyl Complexes

      • Chemistry at the Metal Center

      • Intramolecular Migration of the Germyl Group from the Metal Center

      • Photolysis/Thermolysis of Metal Carbonyl Germyl Complexes

      • Reactivity of Germa-heterocycles

    • Chemistry of the Transition Metal Germanium Double Bond, M[DOUBLE BOND]Ge

  • Organotin Transition Metal Complexes

    • Synthesis of the Transition Metal Tin Single Bond

      • Salt-elimination Reactions between Transition Metal Anions and Tin Halides

      • Synthesis from Transition Metal Complexes and Organotin Anions

      • Elimination of H2, HCl, Amines, Hydrocarbons, Silanes, etc.

      • Addition of HSnR3 to Metal Centers and Related Reactions

      • Insertion of Sn(II) Species into M[BOND]X Bonds

      • Use of Distannane and Distannoxane Reagents

      • Organotin Group Transfer via Sn[BOND]C Bond Cleavage

      • Miscellaneous Reactions

    • Synthesis of Stannylene Complexes

    • The Reactivity of the Transition Metal Tin Single Bond

      • Thermal Stability

      • Photostability

      • Insertion Reactions

      • Metal Tin Bond Cleavage

      • Chemistry at Tin

      • Reactions at the Transition Metal Center

      • Stannyl Group Migrations

      • Photolytic Reactions

      • Other Reactions

      • Synthetic Utility of Tin Copper and Tin Zinc Compounds

    • Reactivity of Metal Stannylenes

  • Organolead Transition Metal Complexes

    • Synthesis of the Transition Metal Lead Single Bond

      • Salt-elimination Reactions between Transition Metallates and Lead Halides

      • Synthesis from Transition Metal Halides and Organoplumbates

      • Oxidative Addition of Pb[BOND]Pb,Pb[BOND]C and Pb[BOND]Cl Bonds to Metal Centers

      • Insertion of Plumbylenes into a Metal Halogen Bond

      • Elimination Reactions

    • Transition Metal Pb(II) Complexes

    • Reactivity of the Transition Metal Lead Single Bond

      • Transition Metal Lead Bond Cleavage

      • Cleavage of the Lead Carbon Bond

      • Thermal and Photochemical Studies

      • Substitutions at the Transition Metal Center

    • Reactivity of the Transition Metal Lead Double Bond

    • Solid State Structures

    • 207Pb NMR Spectroscopy

  • References