19. Synthetic Uses of R3MH (M = Ge, Sn, Pb)

  1. Zvi Rappoport
  1. Michael W. Carland and
  2. Carl H. Schiesser

Published Online: 5 FEB 2003

DOI: 10.1002/0470857188.ch19

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

How to Cite

Carland, M. W. and Schiesser, C. H. (2002) Synthetic Uses of R3MH (M = Ge, Sn, Pb), in The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2 (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857188.ch19

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. School of Chemistry, The University of Melbourne, Victoria, Australia, 3010. Fax: 61-3-9347 5180

Publication History

  1. Published Online: 5 FEB 2003
  2. Published Print: 26 NOV 2002

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471497387

Online ISBN: 9780470857182

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Summary

This chapter contains sections titled:

  • Introduction

  • The Preparation of Novel Trialkylgermanes and Stannanes

    • Trialkylgermanium Hydrides (R3GeH)

    • Trialkyltin Hydrides (R3SnH)

  • Trialkyltin Hydrides as Reagents in Radical Chain Reactions

    • General Aspects

    • Tributyltin, Trimethyltin and Triphenyltin Hydride (Bu3SnH, Me3SnH, Ph3SnH)

      • Free-radical Reduction Chemistry

      • Intermolecular Addition Chemistry

      • Intramolecular Addition (Cyclization) Reactions

      • Tandem/Cascade Cyclization Sequences

      • Free-radical Hydrostannylation Reactions

      • Miscellaneous Radical Reactions

    • Other Tin Hydrides

  • Trialkyltin Hydrides in Non-radical Chemistry

  • Trialkylgermanium and Lead Hydrides in Synthesis

  • Acknowledgement

  • References