20. Trichlorogermane, A New Superacid in Organic Chemistry

  1. Zvi Rappoport
  1. Stanislav Kolesnikov,
  2. Stanislav N. Tandura and
  3. Oleg M. Nefedov

Published Online: 5 FEB 2003

DOI: 10.1002/0470857188.ch20

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

How to Cite

Kolesnikov, S., Tandura, S. N. and Nefedov, O. M. (2002) Trichlorogermane, A New Superacid in Organic Chemistry, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2 (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857188.ch20

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prospect, 119991 Moscow, Russian Federation. Fax: +7(095)135 5328

Publication History

  1. Published Online: 5 FEB 2003
  2. Published Print: 26 NOV 2002

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471497387

Online ISBN: 9780470857182

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Summary

This chapter contains sections titled:

  • Introduction

  • Synthesis, Structure and Physical Properties of Trichlorogermane

  • Acidic and Superacidic Properties of Trichlorogermane

    • Chemical Examples and Determinations

    • Etherates of Trichlorogermane

    • Stable Organic Salts with a GeCl3 Anion

  • Electrochemical Investigation of HGeCl3 and GeCl4

    • Oxidation

    • Reduction

  • Reactions of Trichlorogermane with Organic Halides

  • Reactions of Trichlorogermane with Unsaturated Compounds

    • Ionic and Radical Mechanisms in Reactions of Hydrogermylation

    • Stereochemistry of the Hydrogermylation

    • Chemically Induced Dynamic Nuclear Polarization in Reactions of Hydrogermylation

    • Reactions with Conjugated Dienes

    • Reactions with α,β-unsaturated Carbonyl Compounds

    • Reactions with Cyclopropane Derivatives

  • Double Germylation

    • Discovery and Reactions

    • Double Germylation of 9-Me-anthracene

  • Reactions of HGeCl3 with Aromatic Compounds

    • Reaction with Anisole

    • Reaction with 1,4-dimethoxybenzene

    • Reaction with Diphenyl Ether

    • Reaction with Triphenylamine

    • Reactions with Benzene and Methylbenzenes

    • Reactions with Condensed Aromatics

  • Conclusions

  • References