8. Structural Effects on Germanium, Tin and Lead Compounds

  1. Zvi Rappoport
  1. Marvin Charton

Published Online: 5 FEB 2003

DOI: 10.1002/0470857188.ch8

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2

How to Cite

Charton, M. (2002) Structural Effects on Germanium, Tin and Lead Compounds, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2 (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857188.ch8

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Chemistry Department, School of Liberal Arts and Sciences, Pratt Institute, Brooklyn, New York 11205, USA. Fax: 718-722-7706

Publication History

  1. Published Online: 5 FEB 2003
  2. Published Print: 26 NOV 2002

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471497387

Online ISBN: 9780470857182

SEARCH

Summary

This chapter contains sections titled:

  • The Nature of Structural Effects

    • Introduction

    • Structure–property Quantitative Relationships (SPQR)

  • Electrical Effects

  • Steric Effects

    • Introduction

    • The Nature of Steric Effects

      • Primary Steric Effects

      • Secondary Steric Effects

      • Direct Steric Effects

      • Indirect Steric Effects

      • The Directed Nature of Steric Effects

    • The Monoparametric Model of Steric Effects

      • Steric Classification of Substituents

      • Planar π-bonded Groups

    • Multiparametric Models of Steric Effects

      • The Branching Equations

      • The Segmental Model10b

      • The Composite Model

    • Bond Length Difference As a Factor in Steric Effects

  • Intermolecular Forces

    • Introduction

    • Parameterization of Intermolecular Forces

      • Hydrogen Bonding

      • van der Waals Interactions

      • Charge Transfer Interactions

      • Intermolecular Force Equation

  • Applications

    • Chemical Reactivities (QSRR)

    • Chemical Properties (QSCR)

      • Phase Change Properties

        • Melting Points (Tm)

        • Boiling Points (Tb)

      • Hydrogen Bonding

      • Conformation

    • Physical Properties (QSPR)

      • Dipole Moments of XnMZ4−n

      • Ionization Potentials

      • Infrared A Values

      • NMR Chemical Shifts

    • Bioactivities (QSAR)

  • The Validity of the Estimated Substituent Constants

  • Appendix. Supplementary Glossary

  • References