Chapter 13. Diazotization of Amines and Dediazoniation of Diazonium Ions

  1. Saul Patai
  1. Heinrich Zollinger

Published Online: 4 APR 2003

DOI: 10.1002/047085720X.ch13

Amino, Nitroso, Nitro and Related Groups

Amino, Nitroso, Nitro and Related Groups

How to Cite

Zollinger, H. (1996) Diazotization of Amines and Dediazoniation of Diazonium Ions, in Amino, Nitroso, Nitro and Related Groups (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/047085720X.ch13

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Technisch-Chemisches Laboratorium, Eidgenössische Technische Hochschule (ETH), Zürich, Switzerland. Fax: +41 01 632 1072

Publication History

  1. Published Online: 4 APR 2003
  2. Published Print: 15 SEP 1996

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471951711

Online ISBN: 9780470857205

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Summary

This chapter contains sections titled:

  • Introduction

  • Diazotizations

    • Diazotization with Alkali Nitrite in Aqueous and Concentrated Mineral Acids

    • Isolation of Diazonium Salts

    • Diazotization of 2- and 4-aminophenols

    • Formation of Diazonium Salts under Anhydrous Conditions

    • Mechanism and Kinetics of Rate-limiting Nitrosation Steps

    • Nucleophilic Catalysis and the Transformation Mechanism of N-nitrosoamines into Diazonium Ions

  • Dediazoniations

    • Mechanisms of Dediazoniations

    • Hydro-de-diazoniations

    • Halo-de-diazoniations and Related Reactions

    • Substitutions of the Diazonio Group by Reagents with Reacting C-atoms

    • Hydroxy- and Mercapto-de-diazoniations

    • Substitutions of the Diazonio Group by Carbonyl and Sulfonyl Groups

    • Metallo-de-diazoniations and Related Reactions

    • Photolytic Dediazoniations

  • References