Chapter 3. Chiroptical Properties of Amino Compounds

  1. Saul Patai
  1. Howard E. Smith

Published Online: 4 APR 2003

DOI: 10.1002/047085720X.ch3

Amino, Nitroso, Nitro and Related Groups

Amino, Nitroso, Nitro and Related Groups

How to Cite

Smith, H. E. (1996) Chiroptical Properties of Amino Compounds, in Amino, Nitroso, Nitro and Related Groups (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/047085720X.ch3

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Department of Chemistry, Vanderbilt University, Nashville, Tennessee 37235, USA. Fax: 00 615 322 4936

Publication History

  1. Published Online: 4 APR 2003
  2. Published Print: 15 SEP 1996

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471951711

Online ISBN: 9780470857205

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Summary

This chapter contains sections titled:

  • Introduction

  • Asymmetric Synthesis

    • Synthesis Using Enzymes

    • Reduction of Ketoximes and Ketoxime Ethers with Chiral Metal Hydride Reagents

    • Reduction of Imines with Chiral Metal Hydride Reagents

    • Reduction of Imines with Hydrogen in the Presence of a Chiral Titanium Hydride Complex

    • Amination of Alkenes with Chiral Borohydride Reagents

    • Aziridination of Alkenes with Chiral Diimine-based Catalysts

    • Kinetic Resolution Using a Modified Sharpless Reagent

  • Estimation of Enantiomeric Excess

    • Quantitative Aspects

    • Chromatography Using Chiral Stationary Phases

    • Nuclear Magnetic Resonance Methods

  • Electronic Circular Dichroism (ECD)

    • Amino Chromophore

    • Effect of the Amino Group on the Benzene Chromophore

      • Benzene Sector Rule

      • Benzene Chirality Rule

    • Chromophoric Derivatives

      • N-salicylidene Derivatives and the Salicylidenamino Chirality Rule

      • Exciton Coupled Circular Dichroism (ECCD) Spectra

        • N-benzylidene Derivatives

        • N-benzoyl Derivatives

    • N-nitrosamines

  • Vibrational Optical Activity (VOA)

    • Vibrational Circular Dichroism (VCD)

    • Raman Optical Activity (ROA)

  • References