Chapter 9. Acidity and Basicity

  1. Saul Patai
  1. Silvia Bradamante

Published Online: 4 APR 2003

DOI: 10.1002/047085720X.ch9

Amino, Nitroso, Nitro and Related Groups

Amino, Nitroso, Nitro and Related Groups

How to Cite

Bradamante, S. (1996) Acidity and Basicity, in Amino, Nitroso, Nitro and Related Groups (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/047085720X.ch9

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. CNR, Centro di studio sulla Sintesi e Stereochimica di Speciali Sistemi Organici, c/o Dipartimento di Chimica Organica e Industriale, Università di Milano, via Golgi 19, 20133 Milano, Italia. Fax: 39 2 236.43.69

Publication History

  1. Published Online: 4 APR 2003
  2. Published Print: 15 SEP 1996

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471951711

Online ISBN: 9780470857205

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Summary

This chapter contains sections titled:

  • Abbreviations

  • Introduction

  • Gas-phase Solution Correlation

    • Acidity and Basicity Scales in Solution

      • Proton Transfer in Water and DMSO

      • Complex Formation with Lewis Acids

      • Hydrogen Bonding

    • Acidity and Basicity Scales in the Gas Phase

      • Scales Relative to Proton

      • Metal Cation Binding

      • Organometallic and Organic Cation Binding

      • Anion Binding and Electron Affinities

      • Cationic Hydrogen Bonds

    • Gas Phase–Solution Relationships

  • Nitrogen Bases

    • Amine Derivatives

    • Amidines and Guanidines

    • Amidates and Amides

  • Nitrogen Acids

    • Structural Characterization of Metal Amides in the Solid State and in Solution

    • Amine Derivatives

    • NH Bond Dissociation Energy

    • Carboxamides and Related Compounds

  • Hydroxamic Acid as Amphoteric Systems

  • Heterocycles

  • Nitro Derivatives

    • Nitromethane Derivatives

    • Structure of Nitroalkanes and Their Conjugated Bases

    • Nitroaryl-substituted Methanes

  • References