42. Highly Reactive Small-Ring Monosilacycles and Medium-Ring Oligosilacycles

  1. Zvi Rappoport2 and
  2. Yitzhak Apeloig3
  1. Wataru Ando and
  2. Yoshio Kabe

Published Online: 7 OCT 2003

DOI: 10.1002/0470857250.ch42

The Chemistry of Organic Silicon Compounds, Volume 2

The Chemistry of Organic Silicon Compounds, Volume 2

How to Cite

Ando, W. and Kabe, Y. (1998) Highly Reactive Small-Ring Monosilacycles and Medium-Ring Oligosilacycles, in The Chemistry of Organic Silicon Compounds, Volume 2 (eds Z. Rappoport and Y. Apeloig), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857250.ch42

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Department of Chemistry and the Lise-Meitner Minerva Center for Computational Quantum Chemistry, Technion–Israel Institute of Technology, Haifa 32000, Israel

Author Information

  1. Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305, Japan

Publication History

  1. Published Online: 7 OCT 2003
  2. Published Print: 30 JUL 1998

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471967576

Online ISBN: 9780470857250

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Summary

This chapter contains sections titled:

  • Introduction

  • Silyl Carbene-to-silene Rearrangement and Ring Formation

    • Decomposition of Monosilanyl Diazo Compounds

    • Decomposition of Oligosilanyl Diazo Compounds

    • Oxasiletane and Oxasiletene

    • Spectroscopic Studies of Silenes

    • Decomposition of Bis(silyldiazomethyl)oligosilanes

    • Silabenzene and 6-silafulvenes

  • Ylide and Small-ring Formations by Silylene Reactions with Heteroatoms and Cumulenes

    • Oxa(thia)siliranes and Sila(thio)carbonyl Ylides

    • Siliranes and Alkylidenesiliranes

  • Ring Formation by Wurtz and Diyne Coupling Reactions

    • Heptasila[7]paracyclophane

    • Bisalkylidenesiletanes

  • Ring Formation by Kipping and Gilman Reactions

    • trans-trisilacycloheptene and [3.1.1]Trisilapropellane

    • Oligosilabridged Cyclic Acetylenes

    • Oligosilabridged and Doubly Bridged Allenes and Bisallenes

    • 1,2-disilaacenaphthene and 9,10-disilaanthracene Silyl Dianions

  • References