10. Nanostructured Hybrid Organic–Inorganic Solids from Molecules to Materials

  1. Zvi Rappoport2 and
  2. Yitzhak Apeloig3
  1. Bruno Boury and
  2. Robert J. P. Corriu

Published Online: 18 JUL 2003

DOI: 10.1002/0470857269.ch10

The Chemistry of Organic Silicon Compounds, Volume 3

The Chemistry of Organic Silicon Compounds, Volume 3

How to Cite

Boury, B. and Corriu, R. J. P. (2001) Nanostructured Hybrid Organic–Inorganic Solids from Molecules to Materials, in The Chemistry of Organic Silicon Compounds, Volume 3 (eds Z. Rappoport and Y. Apeloig), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857269.ch10

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Israel Institute of Technology, Haifa, Israel

Author Information

  1. Laboratoire de Chimie Moléculaire et Organisation du Solide, UMR 5637, Université de Montpellier II, CC007, Place E. Bataillon, 34095 Montpellier cedex, France. Fax: 33-467-143-888

Publication History

  1. Published Online: 18 JUL 2003
  2. Published Print: 10 DEC 2001

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471623847

Online ISBN: 9780470857267

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Summary

This chapter contains sections titled:

  • Introduction

  • Nanocomposites Versus Nanostructured Hybrid Materials

    • Nanocomposite Hybrid. An [Organic Host + SiO2 or R′SiO1.5 Matrix] Association

    • Nanostructured Hybrid Material Monocomponent with One Si[BOND]C Bond—Organo-silsesquioxanes R′(SiO1.5)

    • Nanostructured Hybrid Material Monocomponent with at Least Two Si[BOND]C Bonds—Organo-polysilsesquioxanes R′(SiO1.5)n(n≥2)

  • Synthesis of Nanostructured Organo-polysilsesquioxanes R′(SiO1.5)n(n≥2). Some Aspects of Precursors and Gel Chemistry

    • The Family of R′(SiX3)n (n≥2) Precursors

    • Synthesis of the Precursors R′(Si(OR)3)n (n≥2)

    • Particular Aspects of the Chemistry During the Sol-gel Polycondensation of R′(Si(OR)3)n (n≥2)

  • Kinetic Control of the Solid's Characteristics of Nanostructured Organo-polysilsesquioxanes R′(SiO1.5)n (n≥2)

    • Polycondensation and Integrity of the Organic Group

    • Texture/Kinetic Parameters of the Sol-gel Process

    • Effect of the Nature of the Organic Group on the Texture of the Xerogels R′(SiO1.5)n (n≥2)

    • Characteristics of the Surface of Xerogels

  • Organization and Short-range Order in Nanostructured Organo-polysilsesquioxanes R′(SiO1.5)n (n≥2)

    • Chemical Evidence of a Short-range Order

    • Characterization of a Short-range Order

    • Optical Evidences for an Anisotropic Organization in the Xerogels

  • Chemistry Inside the Architecture of the Hybrid Nanostructured Organo-polysilsesquioxanes R′(SiO1.5)n (n≥2)

    • Chemical Stability

    • Inter-activity between the Organic Groups

    • Reactivity/Structure Relationship

    • Xerogels with Catalytic Properties

    • Miscellaneous

  • Nanostructured Organo-polysilsesquioxanes R′(SiO1.5)n (n≥2) as Precursors for Porous Materials

    • Direct Thermal Oxidative Elimination of the Organic Groups

    • Non-oxidative Thermal Elimination of the Organic Groups

    • Elimination of the Organic Groups by Chemical Treatment

  • Shaping of Nanostructured Organo-polysilsesquioxanes R′(SiO1.5)n (n≥2)

    • Monoliths, Aerogels and Thin Films

    • Mesoporous Hybrids (MCM Systems)

  • Some Physical Properties of Nanostructured Organo-polysilsesquioxanes R′(SiO1.5)n(n≥2)

    • Thermal Properties

    • Electrochemical Properties

    • Optical Properties

    • Mechanical Properties

  • General Summary

  • References