17. Kinetic Studies of the Reactions of Si[DOUBLE BOND]C and Si[DOUBLE BOND]Si Bonds

  1. Zvi Rappoport2 and
  2. Yitzhak Apeloig3
  1. Tracy L. Morkin,
  2. Thomas R. Owens and
  3. William J. Leigh

Published Online: 18 JUL 2003

DOI: 10.1002/0470857269.ch17

The Chemistry of Organic Silicon Compounds, Volume 3

The Chemistry of Organic Silicon Compounds, Volume 3

How to Cite

Morkin, T. L., Owens, T. R. and Leigh, W. J. (2001) Kinetic Studies of the Reactions of Si[DOUBLE BOND]C and Si[DOUBLE BOND]Si Bonds, in The Chemistry of Organic Silicon Compounds, Volume 3 (eds Z. Rappoport and Y. Apeloig), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857269.ch17

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Israel Institute of Technology, Haifa, Israel

Author Information

  1. Department of Chemistry, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1. Fax: (1) 905 522-2509

Publication History

  1. Published Online: 18 JUL 2003
  2. Published Print: 10 DEC 2001

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471623847

Online ISBN: 9780470857267

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Summary

This chapter contains sections titled:

  • Introduction

  • Experimental Methods

  • Kinetics and Mechanisms of the Reactions of Silenes

    • Unimolecular Reactions

    • Bimolecular Reactions

      • General Trends

      • Dimerization

      • Nucleophilic Addition

        • Addition of Water and Alcohols

        • Addition of Acetic Acid

        • Addition of Aliphatic Amines

        • Addition of Alkoxysilanes

      • Ene- and [2+2]-addition of Ketones, Aldehydes and Esters

      • Ene-, [2+2]- and [4+2]-cycloaddition of Alkenes and Dienes

      • Other Reactions—Oxygen, Sulphoxides and Halocarbons

      • Solvent Effects on Silene Reactivity

    • Substituent Effects on Silene Reactivity

      • Silenes of the Type (R)MeSi[DOUBLE BOND]CH2 and Me2Si[DOUBLE BOND]CHR

      • 1-silaallenes

  • Kinetics and Mechanisms of the Reactions of Disilenes

    • Unimolecular Reactions

    • Bimolecular Reactions

      • Addition of Alcohols and Phenols

      • [2+4]-, [2+2]- and [2+1]-cycloadditions of Dienes, Carbonyl Compounds and Oxygen

  • Conclusions

  • Appendix: Negative Arrhenius Activation Energies

  • References