2. (Helium I)-Photoelectron Spectra of Silicon Compounds: History and Achievements Concerning their Molecular States

  1. Zvi Rappoport2 and
  2. Yitzhak Apeloig3
  1. H. Bock and
  2. B. Solouki

Published Online: 18 JUL 2003

DOI: 10.1002/0470857269.ch2

The Chemistry of Organic Silicon Compounds, Volume 3

The Chemistry of Organic Silicon Compounds, Volume 3

How to Cite

Bock, H. and Solouki, B. (2003) (Helium I)-Photoelectron Spectra of Silicon Compounds: History and Achievements Concerning their Molecular States, in The Chemistry of Organic Silicon Compounds, Volume 3 (eds Z. Rappoport and Y. Apeloig), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857269.ch2

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Israel Institute of Technology, Haifa, Israel

Author Information

  1. Institute of Inorganic Chemistry, Johann Wolfgang Goethe University, Marie-Curie Street 11, D-60439 Frankfurt am Main, Germany. Fax: 0049-69-798-29188

Publication History

  1. Published Online: 18 JUL 2003
  2. Published Print: 10 DEC 2001

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471623847

Online ISBN: 9780470857267

SEARCH

Summary

This chapter contains sections titled:

  • Introductory Remarks: Photoelectron Spectroscopy Today and the Scope of This Review

  • Real-time Gas Analysis Using Photoelectron Spectroscopic Vertical Ionization Fingerprints

    • Principle of PES Measurement and Some Experimental Details

    • The Molecular State Approach to Silicon Compounds

  • Introductory ‘Classic’ Examples of Photoelectron Spectroscopic Information on Properties of and Bonding in Silicon-containing Molecules

    • The Tremendous Difference in Effective Nuclear Potentials of Carbon and Silicon

    • Charge Delocalization in Polysilane Radical Cations

    • Silicon-substituted Carbon-π-systems: First and Second Order Perturbation

    • One-electron Ionization and One-electron Oxidation of Organosilicon Compounds

    • Sterically Overcrowded Organosilicon Molecules

    • Kinetically Unstable Silicon Intermediates: Detection in Unimolecular Flow Systems by Their PE-spectroscopic Ionization Fingerprints

    • Interim Summary

  • (He I)-photoelectron Spectroscopic Results 1990–2000

    • Organosilicon Compounds Containing Main Group 13 Elements

    • Organosilicon Molecules (Main Group 14 Elements)

      • Silicocene

      • Cation Charge Delocalization in the Si8 Skeleton of Hexakis(Trimethylsilyl) Disilane

      • Organosilicon Cations in Solvents and Their Matrix Isolation

      • Further PE Spectroscopic Investigations of Organosilicon Compounds with Group 14 Elements

    • Organosilicon Molecules Containing Main Group 15 Elements

      • (He I) PE Spectrum of Stable ‘Imidazole’-silylene

      • Sterically Overcrowded Trimethylsilyl-p-phenylenediamines

      • Thermal Generation of Trimethyl Silanimine in the Gas Phase

      • Further PE Spectroscopic Investigations of Organosilicon Compounds with Group 15 Elements

    • Organosilicon Molecules Containing Main Group 16 Elements

      • Oxygen Lone Pair Ionization Energies of Siloxanes

      • Sulfur Lone Pair Ionization Energies of Silthianes

      • Further PE Spectroscopic Investigations of Organosilicon Compounds with Group 16 Elements

    • Silicon Molecules Containing Main Group 17 Elements

      • The PE Spectrum of SiI2—A Novel Triatomic Molecule with a Relativistic Touch

      • PE Spectroscopic Investigations of Organosilicon Compounds with Group 17 Elements

  • Retrospective and Perspectives

  • References and Notes