3. 29Si NMR Experiments in Solutions of Organosilicon Compounds

  1. Zvi Rappoport2 and
  2. Yitzhak Apeloig3
  1. Jan Schraml

Published Online: 18 JUL 2003

DOI: 10.1002/0470857269.ch3

The Chemistry of Organic Silicon Compounds, Volume 3

The Chemistry of Organic Silicon Compounds, Volume 3

How to Cite

Schraml, J. (2001) 29Si NMR Experiments in Solutions of Organosilicon Compounds, in The Chemistry of Organic Silicon Compounds, Volume 3 (eds Z. Rappoport and Y. Apeloig), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470857269.ch3

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Israel Institute of Technology, Haifa, Israel

Author Information

  1. Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, 165 02 Prague, Czech Republic. Fax: 4202 20 92 0661

Publication History

  1. Published Online: 18 JUL 2003
  2. Published Print: 10 DEC 2001

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471623847

Online ISBN: 9780470857267

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Summary

This chapter contains sections titled:

  • Introduction

  • Basic Facts

  • Referencing

  • Solvent Effects

  • Sensitivity Enhancements

    • Selective Polarization Transfer (SPT)

    • Non-selective Polarization Transfers (INEPT, DEPT, PENDANT, PASSADENA and Their Variants)

    • J Cross-polarization (JCP)

  • Line Assignments and Connectivity

    • Correlations

      • 29Si Detected Heteronuclear Correlations

      • Indirectly Detected Heteronuclear Correlations

      • INADEQUATE

      • DQF COSY

      • 29Si[BOND]29Si Couplings, nJ(29Si[BOND]29Si)

    • Triple Resonance

      • 1D Experiments

      • 2D Experiments

      • 3D Experiments

    • Selective Experiments

      • Selective Excitation

      • Selective Detection

  • Determination of Coupling Constants

  • Relaxations

  • Nuclear Overhauser Effect (NOE)

  • Miscellaneous

    • Isotopic Enrichment and Substitution

    • DOSY (Diffusion Ordered SpectroscopY)

    • Quantitative Measurements

    • Ultrahigh Resolution

    • Shift and Relaxation Reagents

  • Common Mistakes and Pitfalls—Comments and Warnings

  • Acknowledgements

  • References