2. NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes
- Marcel Gielen3,
- Rudolph Willem3,
- Bernd Wrackmeyer4
Published Online: 3 AUG 2005
DOI: 10.1002/0470858451.ch2
Copyright © 2004 John Wiley & Sons, Ltd
Book Title
Fluxional Organometallic and Coordination Compounds: Physical Organometallic Chemistry, Volume 4
Additional Information
How to Cite
Gridnev, I. D. and Tok, O. L. (2005) NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes, in Fluxional Organometallic and Coordination Compounds: Physical Organometallic Chemistry, Volume 4 (eds M. Gielen, R. Willem and B. Wrackmeyer), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470858451.ch2
Editor Information
- 3
Free University of Brussels, Belgium
- 4
Universität Bayreuth, Germany
Publication History
- Published Online: 3 AUG 2005
- Published Print: 13 AUG 2004
Book Series:
Book Series Editors:
- Marcel Gielen3,
- Rudolph Willem3,
- Bernd Wrackmeyer4
Series Editor Information
- 3
Free University of Brussels, Belgium
- 4
Universität Bayreuth, Germany
ISBN Information
Print ISBN: 9780470858394
Online ISBN: 9780470858455
- Summary
- Chapter
Keywords:
- fluxional allylboranes;
- borotropic migrations;
- allylic moiety;
- fluxional linear polyunsaturated allylboranes;
- intramolecular dynamics;
- sigmatropic migrations;
- oscillating rearrangement;
- diverse chemoselectivity
Summary
This chapter contains sections titled:
Introduction
Discovery Activation Parameters of [1,3]-B Shifts
Fluxional Linear Polyunsaturated Allylboranes
Dynamic Behavior of Cyclic Allylboranes
Diverse Chemoselectivity of Cyclic Polyunsaturated Organoboranes
Conclusion
References