3. Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR

  1. Marcel Gielen2,
  2. Rudolph Willem2 and
  3. Bernd Wrackmeyer3
  1. Sergei G. Sakharov

Published Online: 3 AUG 2005

DOI: 10.1002/0470858451.ch3

Fluxional Organometallic and Coordination Compounds: Physical Organometallic Chemistry, Volume 4

Fluxional Organometallic and Coordination Compounds: Physical Organometallic Chemistry, Volume 4

How to Cite

Sakharov, S. G. (2004) Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR, in Fluxional Organometallic and Coordination Compounds: Physical Organometallic Chemistry, Volume 4 (eds M. Gielen, R. Willem and B. Wrackmeyer), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470858451.ch3

Editor Information

  1. 2

    Free University of Brussels, Belgium

  2. 3

    Universität Bayreuth, Germany

Author Information

  1. Kurnakov Institute of General and Inorganic Chemistry , Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russia

Publication History

  1. Published Online: 3 AUG 2005
  2. Published Print: 13 AUG 2004

Book Series:

  1. Physical Organometallic Chemistry

Book Series Editors:

  1. Marcel Gielen2,
  2. Rudolph Willem2 and
  3. Bernd Wrackmeyer3

Series Editor Information

  1. 2

    Free University of Brussels, Belgium

  2. 3

    Universität Bayreuth, Germany

ISBN Information

Print ISBN: 9780470858394

Online ISBN: 9780470858455

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Keywords:

  • dynamic NMR spectroscopy;
  • EXSY(exchange spectroscopy) technique;
  • lineshape analysis;
  • Anderson–Kubo–Sack theory;
  • rotational isomerism;
  • variable temperature NMR studies;
  • titanium ketimido compounds;
  • oximato complexes

Summary

This chapter contains sections titled:

  • Introduction

  • Rotational Isomerism in Amido and Ketimido Complexes

  • Dynamic Behavior of d0 Transition Metal Complexes with n-Donor Two-Center Ligands

  • Conclusion

  • References