4. Conformational Mobility in Chelated Square-Planar Rh, Ir, Pd, and Pt Complexes

  1. Marcel Gielen2,
  2. Rudolph Willem2 and
  3. Bernd Wrackmeyer3
  1. Pablo Espinet and
  2. Juan A. Casares

Published Online: 3 AUG 2005

DOI: 10.1002/0470858451.ch4

Fluxional Organometallic and Coordination Compounds: Physical Organometallic Chemistry, Volume 4

Fluxional Organometallic and Coordination Compounds: Physical Organometallic Chemistry, Volume 4

How to Cite

Espinet, P. and Casares, J. A. (2004) Conformational Mobility in Chelated Square-Planar Rh, Ir, Pd, and Pt Complexes, in Fluxional Organometallic and Coordination Compounds: Physical Organometallic Chemistry, Volume 4 (eds M. Gielen, R. Willem and B. Wrackmeyer), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470858451.ch4

Editor Information

  1. 2

    Free University of Brussels, Belgium

  2. 3

    Universität Bayreuth, Germany

Author Information

  1. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, E-47005 Valladolid, Spain

Publication History

  1. Published Online: 3 AUG 2005
  2. Published Print: 13 AUG 2004

Book Series:

  1. Physical Organometallic Chemistry

Book Series Editors:

  1. Marcel Gielen2,
  2. Rudolph Willem2 and
  3. Bernd Wrackmeyer3

Series Editor Information

  1. 2

    Free University of Brussels, Belgium

  2. 3

    Universität Bayreuth, Germany

ISBN Information

Print ISBN: 9780470858394

Online ISBN: 9780470858455

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Keywords:

  • stereoselectivity;
  • ligand coordination;
  • organometallic chemistry;
  • entantiomeric excess (ee);
  • metallacycle;
  • NOESY and ROESY experiments;
  • puckered-ring;
  • meso symmetric envelope

Summary

This chapter contains sections titled:

  • Introduction

  • Conformational Changes in Five-member Metallacycles

  • Conformational Changes in Six-member Metallacycles

  • Conformational Changes in Five- or Six-member Metallacycles Involving Coordinated Olefins

  • Conformational Changes in Seven-member Metallacycles

  • Conformational Changes in Higher Metallacycles

  • Acknowledegment

  • References