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Oxidation Catalysis by Transition Metal Complexes

  1. Robert H. Crabtree

Published Online: 15 MAR 2006

DOI: 10.1002/0470862106.ia173

Encyclopedia of Inorganic Chemistry

Encyclopedia of Inorganic Chemistry

How to Cite

Crabtree, R. H. 2006. Oxidation Catalysis by Transition Metal Complexes. Encyclopedia of Inorganic Chemistry. .

Author Information

  1. Yale University, New Haven, CT, USA

Publication History

  1. Published Online: 15 MAR 2006

Abstract

Oxidation catalysis is reviewed with emphasis on radical versus nonradical pathways, autoxidation, and mechanistic studies. Bioinorganic model catalysts are discussed, including the distinction between monooxygenase and dioxygenase pathways. Some organic synthetic applications as well as applications to green chemistry are discussed. Finally some organometallic oxidation catalysts are discussed.

Keywords:

  • epoxidation;
  • asymmetric catalysis;
  • hydroxylation;
  • peroxides;
  • oxygen