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Gold in Homogeneous Catalysis

  1. Eloása Jiménez-Núñez,
  2. Antonio M. Echavarren

Published Online: 13 JUN 2008

DOI: 10.1002/0470862106.ia459

Encyclopedia of Inorganic Chemistry

Encyclopedia of Inorganic Chemistry

How to Cite

Jiménez-Núñez, E. and Echavarren, A. M. 2008. Gold in Homogeneous Catalysis. Encyclopedia of Inorganic Chemistry. .

Author Information

  1. Institute of Chemical Research of Catalonia (ICIQ), Tarragona, Catalonia, Spain

Publication History

  1. Published Online: 13 JUN 2008

Abstract

The important types of transformations catalyzed by homogeneous Au(I) and Au(III) complexes or salts are reviewed. The reactions are organized mechanistically on the basis of the main functional group being activated by the gold catalyst. Particular emphasis is given on the most general reactions for the formation of C[BOND]C bonds.

Keywords:

  • gold;
  • alkynes;
  • alkenes;
  • enynes;
  • cyclizations;
  • rearrangement;
  • phosphines;
  • N-heterocyclic carbenes