Chapter Four. Compounds of General Interest

  1. Dimitri Coucouvanis

Published Online: 7 APR 2002

DOI: 10.1002/0471224502.ch4

Inorganic Syntheses, Volume 33

Inorganic Syntheses, Volume 33

How to Cite

Coucouvanis, D. (ed) (2002) Compounds of General Interest, in Inorganic Syntheses, Volume 33, John Wiley & Sons, Inc., New York, USA. doi: 10.1002/0471224502.ch4

Editor Information

  1. University of Michigan

Publication History

  1. Published Online: 7 APR 2002
  2. Published Print: 15 FEB 2002

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471208259

Online ISBN: 9780471224501

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Keywords:

  • diphenylmethylenethiophosphinate (MTP) ligand;
  • mesityl-gold(I)complexes;
  • charge transfer sensitizer;
  • platinum (II);
  • dimethylsulfoxide complexes;
  • S4N4;
  • hydrotis(methimazolyl)borate;
  • arsenic(III)bromide;
  • UO2Cl2(OPPh3)2;
  • {RuCl[κ3-HB(pz)](PPh3)2};
  • Re2(μ-H)2(CO)8;
  • zero–valent binuclear nickel complexes;
  • synthetic ribonuclease;
  • carbonyl halide tungsten (II) complexes;
  • Re (I)tricarbonyl complexes;
  • organosilanes;
  • fluorination;
  • seven-coordinate halocarbonyl complexes;
  • IRCl(CS) (PPh3)2

Summary

This chapter comprises Subchapters 25–42 and deals with compounds of general interest in inorganic synthesis. The lengthiest sections cover the diphenylmethylenethiophosphinate (MTP) ligand in gold (I), platinum (II), lead(II), thalium(I), and mercury (II) complexes; the carbonyl halide tungsten (II) complexes of tris(3,5-dimethylpyrazolyl)hydroborate; and fluorination with Me3SNF cyclopentadienyl-substituted group 4 metal fluoride complexes. Other topics include mesityl-gold(I) complexes, tetrasulfur-tetranitride (S4N4), hydrotris(methimazolyl)borate, arsenic(III)bromide, and zero-valence binuclear nickel complexes.