Chapter 4. Characteristic Frequencies of Molecules with Triple Bonds and Cumulated Double Bonds
- Dana W. Mayo,
- Foil A. Miller,
- Robert W. Hannah
Published Online: 10 JUN 2004
DOI: 10.1002/0471690082.ch4
Copyright © 2003 John Wiley & Sons, Inc.
Book Title
Course Notes on the Interpretation of Infrared and Raman Spectra
Additional Information
How to Cite
Hannah, R. W. and Miller, F. A. (2004) Characteristic Frequencies of Molecules with Triple Bonds and Cumulated Double Bonds, in Course Notes on the Interpretation of Infrared and Raman Spectra (eds D. W. Mayo, F. A. Miller and R. W. Hannah), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0471690082.ch4
Publication History
- Published Online: 10 JUN 2004
- Published Print: 7 MAY 2004
ISBN Information
Print ISBN: 9780471248231
Online ISBN: 9780471690085
- Summary
- Chapter
Keywords:
- triple bonds;
- cumulated double bonds;
- acetylenes;
- C
![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
H stretch; - C
![[TRIPLE BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8fd.gif)
C stretch; - nitriles;
- allenes;
- ketenes;
- isocyanates
Summary
Chapter 4 extends the discussion of hydrocarbon frequencies to alkenes and covers both open chain and cyclic olefins. The 3000 cm−1 rule is introduced. The displacement of the atoms leading to alkene group frequencies are described. The use of these modes to establish the substitution pattern of the unsaturation is covered. The influence of conjugation and polarization is explored.