4. Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions

  1. Robert H. Crabtree

Published Online: 27 JAN 2005

DOI: 10.1002/0471718769.ch4

The Organometallic Chemistry of the Transition Metals, Fourth Edition

The Organometallic Chemistry of the Transition Metals, Fourth Edition

How to Cite

Crabtree, R. H. (2005) Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions, in The Organometallic Chemistry of the Transition Metals, Fourth Edition, John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0471718769.ch4

Author Information

  1. Yale University, New Haven, Connecticut, USA

Publication History

  1. Published Online: 27 JAN 2005
  2. Published Print: 15 APR 2005

ISBN Information

Print ISBN: 9780471662563

Online ISBN: 9780471718765

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Keywords:

  • carbonyls;
  • phosphine complexes;
  • interchange mechanism of substitution

Summary

This chapter contains sections titled:

  • Metal Complexes of CO, RNC, CS, and NO

  • Phosphines and Related Ligands

  • Dissociative Substitution

  • Associative Mechanism

  • Redox Effects, the I Mechanism, and Rearrangements in Substitution

  • Photochemical Substitution

  • Steric and Solvent Effects in Substitution