8. Nucleophilic and Electrophilic Addition and Abstraction

  1. Robert H. Crabtree

Published Online: 27 JAN 2005

DOI: 10.1002/0471718769.ch8

The Organometallic Chemistry of the Transition Metals, Fourth Edition

The Organometallic Chemistry of the Transition Metals, Fourth Edition

How to Cite

Crabtree, R. H. (2005) Nucleophilic and Electrophilic Addition and Abstraction, in The Organometallic Chemistry of the Transition Metals, Fourth Edition, John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0471718769.ch8

Author Information

  1. Yale University, New Haven, Connecticut, USA

Publication History

  1. Published Online: 27 JAN 2005
  2. Published Print: 15 APR 2005

ISBN Information

Print ISBN: 9780471662563

Online ISBN: 9780471718765

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Keywords:

  • umpolung;
  • radical abstraction;
  • neutrophilic and electrophilic addition

Summary

This chapter contains sections titled:

  • Nucleophilic Addition to CO

  • Nucleophilic Addition to Polyene and Polyenyl Ligands

  • Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls

  • Electrophilic Addition

  • Electrophilic Abstraction of Alkyl Groups

  • Single-Electron Transfer Pathways

  • Reactions of Organic Free Radicals with Metal Complexes