Free Radical Generation by Reactions of Ions with Molecules

  1. E. T. Denisov,
  2. T. G. Denisova and
  3. T. S. Pokidova

Published Online: 28 JAN 2005

DOI: 10.1002/0471721476.ch15

Handbook of Free Radical Initiators

Handbook of Free Radical Initiators

How to Cite

Denisov, E. T., Denisova, T. G. and Pokidova, T. S. (2003) Free Radical Generation by Reactions of Ions with Molecules, in Handbook of Free Radical Initiators, John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0471721476.ch15

Publication History

  1. Published Online: 28 JAN 2005
  2. Published Print: 21 MAR 2003

ISBN Information

Print ISBN: 9780471207535

Online ISBN: 9780471721475

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Keywords:

  • free radicals;
  • Gibbs energies;
  • liquid-phase oxidation

Summary

This chapter includes the following topics:

  • Decomposition of Hydrogen Peroxide Catalyzed by Transition Metal Ions

  • Catalysis by Ions and Complexes of Transition Metals in Liquid-Phase Oxidation of Organic Compounds

  • Reactions of Free Radicals with Transition Metal Ions

  • Oxidation of Transition Metal Ions by Dioxygen

  • Oxidation of Organic Compounds by Transition Metal Ions

  • Reduction of Peroxides by Radical Anions