Chapter 6d. Asymmetric Oxidations and Related Reactions: Catalytic Asymmetric Dihydroxylation—Discovery and Development

  1. Iwao Ojima
  1. Roy A. Johnson1,
  2. K. Barry Sharpless2

Published Online: 14 FEB 2005

DOI: 10.1002/0471721506.ch11

Book Title

Catalytic Asymmetric Synthesis, Second Edition

Catalytic Asymmetric Synthesis, Second Edition

Additional Information

How to Cite

Johnson, R. A. and Sharpless, K. B. (2005) Asymmetric Oxidations and Related Reactions: Catalytic Asymmetric Dihydroxylation—Discovery and Development, in Catalytic Asymmetric Synthesis, Second Edition (ed I. Ojima), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0471721506.ch11

Editor Information

  1. Department of Chemistry, State University of New York at Stony Brook, Stony Brook, NY 11794-3400, USA

Author Information

  1. 1

    The Upjohn Company, Kalamazoo, Michigan, USA

  2. 2

    The Scripps Research Institute, La Jolla, California, USA

Publication History

  1. Published Online: 14 FEB 2005
  2. Published Print: 17 JUL 2000

ISBN Information

Print ISBN: 9780471298052

Online ISBN: 9780471721505

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Keywords:

  • catalytic asymmetric dihydroxylation (ADs);
  • primary catalytic cycle;
  • enantioselectivity mnemonic

Summary

This chapter contains sections titled:

  • Introduction

  • General Features of Osmium-Catalyzed Asymmetric Dihydroxylation

  • Catalytic Asymmetric Dihydroxylations by Olefin Substitution Pattern

  • Diol Activation

  • Conclusion

  • References

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