Chapter 4. Asymmetric Carbometallations

  1. Iwao Ojima
  1. Ei-ichi Negishi

Published Online: 14 FEB 2005

DOI: 10.1002/0471721506.ch5

Book Title

Catalytic Asymmetric Synthesis, Second Edition

Catalytic Asymmetric Synthesis, Second Edition

Additional Information

How to Cite

Negishi, E.-i. (2005) Asymmetric Carbometallations, in Catalytic Asymmetric Synthesis, Second Edition (ed I. Ojima), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0471721506.ch5

Editor Information

  1. Department of Chemistry, State University of New York at Stony Brook, Stony Brook, NY 11794-3400, USA

Author Information

  1. Department of Chemistry, Purdue University, 1393 Brown Laboratories, West Lafayette, IN 47907-1393, USA

Publication History

  1. Published Online: 14 FEB 2005
  2. Published Print: 17 JUL 2000

ISBN Information

Print ISBN: 9780471298052

Online ISBN: 9780471721505

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Keywords:

  • carbometallation;
  • dehydrometallation;
  • Zr-catalyzed enantioselective carbomagnesation-elimination

Summary

This chapter contains sections titled:

  • Introduction

  • Historical Background and Scope

  • Zirconium-Catalyzed Enantioselective Monocarboalumination of Unactivated Alkenes

  • Zirconium-Catalyzed Enantioselective Cyclic Carbometallation of Allylic Ethers, Alcohols, Amines, and Sulfides

  • Titanium-Catalyzed Enantioselective Enyne Bicyclization-Carbonylation

  • Conclusion

  • References

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