Chapter 6a. Asymmetric Oxidations and Related Reactions: Catalytic Asymmetric Epoxidation of Allylic Alcohols

  1. Iwao Ojima
  1. Roy A. Johnson1,
  2. K. Barry Sharpless2

Published Online: 14 FEB 2005

DOI: 10.1002/0471721506.ch7

Book Title

Catalytic Asymmetric Synthesis, Second Edition

Catalytic Asymmetric Synthesis, Second Edition

Additional Information

How to Cite

Johnson, R. A. and Sharpless, K. B. (2005) Asymmetric Oxidations and Related Reactions: Catalytic Asymmetric Epoxidation of Allylic Alcohols, in Catalytic Asymmetric Synthesis, Second Edition (ed I. Ojima), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0471721506.ch7

Editor Information

  1. Department of Chemistry, State University of New York at Stony Brook, Stony Brook, NY 11794-3400, USA

Author Information

  1. 1

    The Upjohn Company, Kalamazoo, Michigan, USA

  2. 2

    The Scripps Research Institute, La Jolla, California, USA

Publication History

  1. Published Online: 14 FEB 2005
  2. Published Print: 17 JUL 2000

ISBN Information

Print ISBN: 9780471298052

Online ISBN: 9780471721505

SEARCH

CHAPTER TOOLS

Get PDF (2668K)

Keywords:

  • asymmetric oxidations;
  • diasteriofacial selectivity;
  • catalyzed asymmetric epoxidation

Summary

This chapter contains sections titled:

  • Introduction

  • Fundamental Elements of Ti-Tartrate Catalyzed Asymmetric Epoxidation

  • Reaction Variables for Ti-Tartrate Catalyzed Asymmetric Epoxidation

  • Sources of Allylic Alcohols

  • Asymmetric Epoxidation by Substrate Structure

  • Mechanism of Ti-Tartrate Catalyzed Asymmetric Epoxidation

  • Other Asymmetric Epoxidations and Oxidations Catalyzed by Titanium Complexes

  • Conclusion

  • References

Get PDF (2668K)