34. Main Concepts of Elementary Reaction Act Theory

  1. V. S. Bagotsky

Published Online: 5 DEC 2005

DOI: 10.1002/047174199X.ch34

Fundamentals of Electrochemistry, Second Edition

Fundamentals of Electrochemistry, Second Edition

How to Cite

Bagotsky, V. S. (2005) Main Concepts of Elementary Reaction Act Theory, in Fundamentals of Electrochemistry, Second Edition, John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/047174199X.ch34

Author Information

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

Publication History

  1. Published Online: 5 DEC 2005
  2. Published Print: 21 OCT 2005

ISBN Information

Print ISBN: 9780471700586

Online ISBN: 9780471741992

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Keywords:

  • Franck–Condon principle;
  • electrochemical electron transfer;
  • Landau–Zener probability of electron transition

Summary

This chapter contains sections titled:

  • Outer-Sphere Electron Transfer Reactions in the Bulk Solution

  • Adiabatic and Nonadiabatic Reactions

  • Electrochemical Electron Transfer

  • Electrochemical Adiabaticity Parameter. Medium Dynamics vs. Static Distribution

  • Adiabatic Electrochemical Electron Transfer Reactions

  • Electric Double-Layer Effects on the Elementary Act of Electron Transfer

  • Bond-Breaking Electron Transfer

  • Reorganization Energy of the Medium and the Frequency Factor

  • Electrochemical Proton Transfer