6. Compositional and Structural Irregularities of Macromolecular Metal Complexes

  1. Alaa S. Abd-El-Aziz2,
  2. Charles E. Carraher Jr.3,
  3. Charles U. Pittman Jr.4 and
  4. Martel Zeldin5
  1. Anatolii D. Pomogailo and
  2. Gulzhian I. Dzhardimalieva

Published Online: 19 OCT 2005

DOI: 10.1002/0471747319.ch6

Macromolecules Containing Metal and Metal-Like Elements: Transition Metal-Containing Polymers, Volume 6

Macromolecules Containing Metal and Metal-Like Elements: Transition Metal-Containing Polymers, Volume 6

How to Cite

Pomogailo, A. D. and Dzhardimalieva, G. I. (2005) Compositional and Structural Irregularities of Macromolecular Metal Complexes, in Macromolecules Containing Metal and Metal-Like Elements: Transition Metal-Containing Polymers, Volume 6 (eds A. S. Abd-El-Aziz, C. E. Carraher, C. U. Pittman and M. Zeldin), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0471747319.ch6

Editor Information

  1. 2

    Department of Chemistry, The University of Winnipeg, Winnipeg, Manitoba, R3B 2E9, Canada

  2. 3

    Department of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, FL 33431 and Florida Center for Environmental Studies, Palm Beach Gardens, FL 33410, Florida, USA

  3. 4

    Department of Chemistry, Mississippi State University, Mississippi State, Mississippi, USA

  4. 5

    Department of Chemistry, University of Richmond, Richmond, Virginia, USA

Author Information

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Cherno-golovka, Moscow Region 142432, Russia

Publication History

  1. Published Online: 19 OCT 2005
  2. Published Print: 7 OCT 2005

ISBN Information

Print ISBN: 9780471684459

Online ISBN: 9780471747314

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Keywords:

  • solid-state interactions;
  • redox of transition metals;
  • topochemistry;
  • copolymer;
  • diamagnetic complexes;
  • metallopolymers;
  • macroligands;
  • macroligand decomposition;
  • conformational changes;
  • configurational changes

Summary

The changes in polymer configuration and conformation when metal-containing reactants interact with already formed polymers. Experimental and theoretical basis for these structural changes is reviewed. Topochemical changes are defined and discussed.