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Thermoelectricity

  1. Martin Gärtner,
  2. Wilfried Hermes,
  3. Panneerselvam Marudhachalam,
  4. Martin Schidleja,
  5. Kerstin Schierle-Arndt

Published Online: 15 JUL 2012

DOI: 10.1002/14356007.a26_621.pub2

Ullmann's Encyclopedia of Industrial Chemistry

Ullmann's Encyclopedia of Industrial Chemistry

How to Cite

Gärtner, M., Hermes, W., Marudhachalam, P., Schidleja, M. and Schierle-Arndt, K. 2012. Thermoelectricity. Ullmann's Encyclopedia of Industrial Chemistry.

Author Information

  1. BASF SE, Ludwigshafen, Germany

Publication History

  1. Published Online: 15 JUL 2012

The article contains sections titled:

1.Introduction
2.Theory
2.1.Definition of Thermoelectric Parameters
2.2.Power Generation
2.3.Peltier Cooling
2.4.Thomson Effect
2.5.Measurement of Thermoelectric Parameters
3.Thermoelectric Materials
3.1.State-of-the-Art Materials
3.2.New Materials
4.Nanothermoelectrics
4.1.Thin Film Superlattices
4.2.Nanocomposites
4.3.Challenges and Perspectives for Nanothermoelectrics
5.Application of Thermoelectric Devices
6.Economic Aspects


Thermoelectricity is the conversion of thermal energy into electrical power and vice versa. Industrial importance has mainly its use for special cooling devices, but it can also be applied for waste heat recovery. The latter drives a huge interest in this technology due to the need for energy efficiency and reduction of CO2-emissions. However, for a broad application the technology has to overcome several drawbacks regarding efficiency and costs.

This article describes the physical background of the technology, the principle of the devices, the materials used, some current trends to improve the technology, and important applications.