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Combinatorial Methods in Catalysis and Materials Science

  1. Oliver Brümmer1,
  2. Keith A. Hall2,
  3. Margarete Leclerc3,
  4. Silvia E. Lee4,
  5. Vince Murphy5

Published Online: 15 JAN 2003

DOI: 10.1002/14356007.f07_f02

Ullmann's Encyclopedia of Industrial Chemistry

Ullmann's Encyclopedia of Industrial Chemistry

How to Cite

Brümmer, O., Hall, K. A., Leclerc, M., Lee, S. E. and Murphy, V. 2003. Combinatorial Methods in Catalysis and Materials Science. Ullmann's Encyclopedia of Industrial Chemistry. .

Author Information

  1. 1

    Symyx Technologies, Inc., Santa Clara, CA 95051, USA

  2. 2

    Symyx Technologies, Inc., Santa Clara, CA 95051, USA

  3. 3

    Symyx Technologies, Inc., Santa Clara, CA, USA

  4. 4

    Symyx Technologies, Inc., Santa Clara, CA, USA

  5. 5

    Symyx Technologies, Inc., Santa Clara, CA, USA

Publication History

  1. Published Online: 15 JAN 2003

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Abstract

The article contains sections titled:

1.Introduction
2.Enzyme Mimetics and Metal Complexes as Enzyme Mimetics
2.1.Combinatorial Libraries of Catalysts as Enzyme Mimetics
2.2.Combinatorial Synthesis Enzyme Mimetics
2.2.1.Hydrolytically Active Metal Complexes
2.2.2.Evolutionary Solid-Phase Synthesis of Oxygenase Mimics
2.2.3.Libraries of Organic Acylation Catalysts
3.Combinatorial Catalysis in Asymmetric Synthesis
3.1.Combinatorial Catalyst Libraries in Enantioselective Additions of Dialkylzinc Reagents
3.2.Ligands for the Lewis Acid-Catalyzed Asymmetric Aza Diels - Alder Reaction
3.3.Divergent Ligand Synthesis for Enantioselective Alkylations
3.4.Chiral Phosphine Ligands for Asymmetric Hydrogenation
3.5.Asymmetric Reactions Catalyzed by Schiff Base-Type Ligands: the Positional Scanning Approach
3.6.Identification of Novel Catalysts for Asymmetric Epoxidations by the Positional Scanning Approach
4.Multidimensional Combinatorial Screening for the Identification of Novel Catalysts
4.1.Catalyst Discovery and Optimization Using Catalyst Arrays
4.2.Parallel Array Screening for Catalyst Optimization Using Discovery and Focused Ligand Libraries
5.One-Pot, Multi-Substrate Screening
6.Combinatorial Approaches to Olefin Polymerization Catalysts
7.Combinatorial Inorganic Catalysis
7.1.Combinatorial Libraries of Homogeneous Polyoxometalate-Based Catalysts
7.2.Combinatorial Libraries and High-Throughput Screening of Heterogenous Polyoxometalate Catalysts
8.Combinatorial Heterogeneous Catalysis
8.1.Oxidative Dehydrogenation of Ethane
8.2.Oxidative Dehydrogenation of Propane
8.3.Catalytic Oxidation of CO and Reduction of NO
9.Combinatorial Electrocatalysis
9.1.Electrocatalysts for Fuel Cells
9.2.Combinatorial Electrosynthesis
10.High-throughput Screening Tools for Catalysis
11.Combinatorial Solid-State Materials Science
11.1.Materials Library Synthesis
11.1.1.Vapor Deposition Techniques
11.1.2.Alternative Library Synthesis Techniques
11.2.High-Throughput Screening for Materials
11.2.1.Optical Screening
11.2.2.X-Ray Characterization
11.3.Applications of Materials
11.3.1.Superconductivity
11.3.2.Ferromagnetic Semiconductors
11.3.3.Magnetoresistant Materials
11.3.4.Dielectric and Ferroelectric Materials
11.3.5.Luminescent Materials
12.Organic Materials and Polymers
12.1.Schiff Bases for Nonlinear Optical (NLO) Materials
12.2.Artificial Receptors for Small Organic Molecules
12.3.New Materials for the Separation of Enantiomers
12.4.Molecular Imprinting
12.5.Polymer Topologies and Functionalization
13.Summary and Outlook