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Catalysis, Homogeneous

  1. Arno Behr

Published Online: 15 SEP 2010

DOI: 10.1002/14356007.o05_o01

Ullmann's Encyclopedia of Industrial Chemistry

Ullmann's Encyclopedia of Industrial Chemistry

How to Cite

Behr, A. 2010. Catalysis, Homogeneous. Ullmann's Encyclopedia of Industrial Chemistry. .

Author Information

  1. Technische Universität Dortmund, Dortmund, Germany

Publication History

  1. Published Online: 15 SEP 2010

Chemistry Terms

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Abstract

The article contains sections titled:

1.Definition
2.History
3.Mechanistic Fundamentals
3.1.Ligands
3.2.Changes in Oxidation State
3.3.Changes in Coordination Number and Coordination Geometry
3.4.Catalytic Elementary Steps
4.Metals and Ligands in Homogeneous Catalysis
4.1.Transition Metals
4.2.Ligand Properties
4.2.1.Ligand Basicity
4.2.2.Steric Demand of Ligands
4.2.3.Asymmetric Ligands
5.Important Industrial Applications
5.1.Hydroformylation
5.2.Carbonylation
5.3.Oligomerization
5.3.1.Oligomerization of Alkenes
5.3.2.Oligomerization of 1,3-Dienes
5.3.3.Oligomerization of Alkynes
5.3.4.Co-oligomerization
5.4.Telomerization
5.5.Polymerization
5.6.Hydrocyanation
5.7.Coupling Reactions with Aromatics
5.8.Metathesis
5.9.Hydrogenation
5.10.Oxidation
5.11.Amination and Hydroamination
5.12.Isomerization

Featured Compounds

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  1. 1 - 8
Compound 8
Molecular Weight:559.56
Molecular Formula:C21H27Cl2N2ORuS2
InChIKey:OTGYBIOVVQXCMC-UHFFFAOYSA-L
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Compound 4
Molecular Weight:703.8
Molecular Formula:C30H48Cl2N2PRuS2
InChIKey:OQFCRXDUWXDRKJ-UHFFFAOYSA-L
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Compound 6
Molecular Weight:483.46
Molecular Formula:C15H23Cl2N2ORuS2
InChIKey:NEELELZZOWTUBR-UHFFFAOYSA-L
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Compound 2
Molecular Weight:925.09
Molecular Formula:C51H78Cl2P2Ru
InChIKey:WXMAVLJYRWDLHW-UHFFFAOYSA-L
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Compound 5
Molecular Weight:705.81
Molecular Formula:C30H50Cl2N2PRuS2
InChIKey:RASXGGXKTTUBRT-UHFFFAOYSA-L
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Compound 7
Molecular Weight:528.46
Molecular Formula:C15H22Cl2N3O3RuS2
InChIKey:MCGBBCOQLFKMIZ-UHFFFAOYSA-L
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Compound 1
Molecular Weight:765.53
Molecular Formula:C30H35F12MoNO2
InChIKey:SREMDTDVHCUUIZ-UHFFFAOYSA-N
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Compound 3
Molecular Weight:822.96
Molecular Formula:C43H72Cl2P2Ru
InChIKey:PNPBGYBHLCEVMK-UHFFFAOYSA-L
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