This work was supported by the state of Baden-Württemberg (Margarete-von-Wrangell habilitation fellowship for S.D., Landesgraduierten fellowship for M.M.), the Deutsche Forschungsgemeinschaft, and the Fonds der Chemischen Industrie. We thank Prof. D. Fenske for his generous support of our research activities, and Prof. R. Ahlrichs for provision of computational resources.
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Communication
Reactivity of Chalcogenostannate Salts: Unusual Synthesis and Structure of a Compound Containing Ternary Cluster Anions [Co4(μ4-Se)(SnSe4)4]10−†
Article first published online: 12 NOV 2002
DOI: 10.1002/1521-3773(20021115)41:22<4269::AID-ANIE4269>3.0.CO;2-8
© 2002 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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41:22<>1.0.CO;2-D/asset/cover.gif?v=1&s=9f9bc10e8a218d7551aa445f7a599af703893f44 "Angewandte Chemie International Edition")
Angewandte Chemie International Edition
Volume 41, Issue 22, pages 4269–4272, November 15, 2002
Additional Information
How to Cite
Zimmermann, C., Melullis, M. and Dehnen, S. (2002), Reactivity of Chalcogenostannate Salts: Unusual Synthesis and Structure of a Compound Containing Ternary Cluster Anions [Co4(μ4-Se)(SnSe4)4]10−. Angew. Chem. Int. Ed., 41: 4269–4272. doi: 10.1002/1521-3773(20021115)41:22<4269::AID-ANIE4269>3.0.CO;2-8
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Publication History
- Issue published online: 12 NOV 2002
- Article first published online: 12 NOV 2002
- Manuscript Received: 21 JUN 2002
- Abstract
- Article
- References
- Cited By
Keywords:
- chalcogens;
- cluster compounds;
- cobalt;
- density functional calculations;
- stannates;
- structure elucidation
41:22<4269::AID-ANIE4269>3.0.CO;2-8/asset/image_m/mcontent.gif?v=1&s=dd35dd5e9646806ea0bb5c14a299b9c8b271fb9c "Thumbnail image of graphical abstract")
A water and methanol mixture permits the transfer of the tin–chalcogen substructure of chalcogenostannate anions into the coordination sphere of transition-metal ions without decomposition. The reaction of K4[SnSe4] with [Co(en)3]Cl3 yields compound 1, which contains highly charged, purely inorganic ternary anions.