Chapter 6. O–H Activation and Addition to Unsaturated Systems

  1. Prof. Dr. Antonio Togni and
  2. Prof. Dr. Hansjörg Grützmacher
  1. Prof. Dr. Kazuhide Tani and
  2. Yasutaka Kataoka

Published Online: 8 OCT 2001

DOI: 10.1002/3527600159.ch6

Catalytic Heterofunctionalization

Catalytic Heterofunctionalization

How to Cite

Tani, K. and Kataoka, Y. (2001) O–H Activation and Addition to Unsaturated Systems, in Catalytic Heterofunctionalization (eds A. Togni and H. Grützmacher), Wiley-VCH Verlag GmbH, Weinheim, FRG. doi: 10.1002/3527600159.ch6

Editor Information

  1. Department of Chemistry Swiss Federal Institute of Technology ETH-Hönggerberg CH-8093 Zürich Switzerland

Author Information

  1. Department of Chemistry Graduate School of Engineering Science Osaka University, Toyonaka Osaka 560-8531 Japan

Publication History

  1. Published Online: 8 OCT 2001
  2. Published Print: 28 SEP 2001

ISBN Information

Print ISBN: 9783527302345

Online ISBN: 9783527600151

SEARCH

Keywords:

  • O–H activation;
  • addition;
  • unsaturated systems;
  • metathesis;
  • activation of water;
  • activation of alcohols;
  • activation of carboxylic acids;
  • water gas shift reactions;
  • Wacker-type reactions;
  • methanolysis of nitrile;
  • reductive dimerization;
  • transfer hydrogenation;
  • silanone generation

Summary

  • Introduction

  • Transition Metal Complexes Resulting from the Activation of O–H Bonds and Reaction with Related Complexes

    • Preparation of Hydrido(hydroxo), Hydrido(alkoxo), and Hydrido(carboxo) Complexes by Metathesis

    • Complexes Resulting from Activation of Water: Hydrido(hydroxo) Complexes

    • Complexes Resulting from Activation of Alcohols: Hydrido(alkoxo) Complexes

    • Complexes Resulting from Activation of Carboxylic Acids: Hydrido(carboxylato) Complexes

    • Reaction of Hydrido(hydroxo), Hydrido(alkoxo) and Hydrido(carboxylato) Complexes

  • Catalytic Reactions Involving Activation of O–H Bonds

    • Water Gas Shift Reactions

    • Wacker-type Reactions

    • Hydration, Alcoholation and the Related Reactions of Unsaturated Compounds

    • Hydration and Methanolysis of Nitrile

    • Addition of O–H Bonds across Alkenes and Related Reactions

    • Addition of O–H Bonds across Alkynes

    • Addition of O–H Bonds to Methylenecyclopropane

    • Addition of Carboxylic Acids to Unsaturated Compounds

    • H–D Exchange Reaction

    • Miscellaneous

    • Reductive Dimerization of Alkynes

    • Transfer Hydrogenation of Unsaturated Compounds

    • Transition Metal-Catalyzed Silanone Generation