Chapter 8. Hydrozirconation

  1. Prof. Dr. Antonio Togni and
  2. Prof. Dr. Hansjörg Grützmacher
  1. Dr. Alain Igau

Published Online: 8 OCT 2001

DOI: 10.1002/3527600159.ch8

Catalytic Heterofunctionalization

Catalytic Heterofunctionalization

How to Cite

Igau, A. (2001) Hydrozirconation, in Catalytic Heterofunctionalization (eds A. Togni and H. Grützmacher), Wiley-VCH Verlag GmbH, Weinheim, FRG. doi: 10.1002/3527600159.ch8

Editor Information

  1. Department of Chemistry Swiss Federal Institute of Technology ETH-Hönggerberg CH-8093 Zürich Switzerland

Author Information

  1. Laboratoire de Chimie de Coordination Du CNRS UPR 8241 205, route de Narbonne 31077 Toulouse Cedex 04 France

Publication History

  1. Published Online: 8 OCT 2001
  2. Published Print: 28 SEP 2001

ISBN Information

Print ISBN: 9783527302345

Online ISBN: 9783527600151

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Keywords:

  • hydrozirconation;
  • alkenes;
  • allenes;
  • alkynes;
  • terminal alkynes;
  • internal alkynes;
  • heteropolar multiple bonds;
  • relative reaction;
  • zirconocene complexes

Summary

  • Introduction

  • Zirconium Hydrides

  • Hydrozirconation across Carbon-Carbon Multiple Bonds

    • Hydrozirconation across Carbon-Carbon Double Bonds

    • Hydrozirconation of Alkenes

    • Hydrozirconation of Allenes

    • Hydrozirconation of Alkynes

    • Hydrozirconation of Terminal Alkynes

    • Hydrozirconation of Internal Alkynes

    • Hydrozirconation across Heteropolar Multiple Bonds

  • Chemoselectivity and Functional Group Compatibility

    • Relative Reactivity of C[TRIPLE BOND]C versus C[DOUBLE BOND]C

    • Relative Reactivity of C[TRIPLE BOND]C and C[DOUBLE BOND]C versus C[TRIPLE BOND]N

    • Relative Reactivity of C[TRIPLE BOND]C and C[DOUBLE BOND]C versus carbonyl functions

  • Bimetallic Transition Metal-Zirconocene Complexes from Zirconium Hydrides

  • Zirconocene Hydrides and Related Derivatives as Catalyst

  • Hydrozirconation: Conclusion and Perspectives