Chapter 4. Binding and Activation of Dioxygen by Biomimetic Metal Complexes

  1. Waldemar Adam
  1. Ernst-G. Jäger,
  2. Jutta Knaudt,
  3. Kerstin Schuhmann and
  4. Anka Guba

Published Online: 30 JUN 2005

DOI: 10.1002/3527600396.ch12

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

How to Cite

Jäger, E.-G., Knaudt, J., Schuhmann, K. and Guba, A. (2000) Binding and Activation of Dioxygen by Biomimetic Metal Complexes, in Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer (ed W. Adam), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527600396.ch12

Editor Information

  1. Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

Author Information

  1. Institut für Anorganische und Analytische Chemie, Universität Jena, August-Bebel-Strasse 2, D-07743 Jena, Germany

Publication History

  1. Published Online: 30 JUN 2005
  2. Published Print: 11 SEP 2000

ISBN Information

Print ISBN: 9783527271504

Online ISBN: 9783527600397

SEARCH

Keywords:

  • biomimetic metal complexes;
  • metal(II) complexes;
  • binding;
  • dioxygen;
  • gas volumetric investigation;
  • redox potentials;
  • Lewis acidity;
  • spin ground state;
  • oxygenation;
  • catalytic activation

Summary

This chapter contains sections titled:

  • Introduction

  • Complexes of New Chiral Ligands

  • Binding of Dioxygen by Metal(II) Complexes

    • Gas Volumetric Investigation of Dioxygen Uptake

    • Redox Potentials, Lewis Acidity, and Spin Ground State

    • Cobalt Complexes: Coupled Equilibria of Oxygenation

    • Complexes of Iron and Manganese: Irreversible Oxygenation

  • Catalytic Activation of Dioxygen

    • General Remarks: Oxidation of Hydroquinone

    • The Role of Special Structural Features: Active and Inactive FeTAA Complexes

  • New [N3,O]-, and [N3,O2]-Coordinated Cobalt(II) Complexes

    • Syntheses and Structures

    • Reaction with Dioxygen

  • References