Chapter 3. Near-UV Photolysis of Singlet Oxygen Generated by Energy Transfer from Aromatic Molecules in Rare-Gas Matrices

  1. Waldemar Adam
  1. Murthy S. Gudipati,
  2. Robert Wagner,
  3. Martin Kalb and
  4. Andreas Klein

Published Online: 30 JUN 2005

DOI: 10.1002/3527600396.ch29

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

How to Cite

Gudipati, M. S., Wagner, R., Kalb, M. and Klein, A. (2000) Near-UV Photolysis of Singlet Oxygen Generated by Energy Transfer from Aromatic Molecules in Rare-Gas Matrices, in Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer (ed W. Adam), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527600396.ch29

Editor Information

  1. Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

Author Information

  1. Institut für Physikalische Chemie, Universität zu Köln, Luxemburger Strasse 116, D-50939 Köln, Germany

Publication History

  1. Published Online: 30 JUN 2005
  2. Published Print: 11 SEP 2000

ISBN Information

Print ISBN: 9783527271504

Online ISBN: 9783527600397

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Keywords:

  • near-UV photolysis;
  • spectroscopy;
  • photochemistry;
  • rare gas matrices;
  • PAH;
  • anthracene-9,10-endoperoxide;
  • PAH/O2 CCs;
  • laser photolysis;
  • APO;
  • DMAPO;
  • atmospheric chemistry

Summary

This chapter contains sections titled:

  • Introduction

  • Experimental Details

  • Spectroscopy and Photochemistry of Isolated Species in Ar Matrices

    • O2 in Rare Gas Matrices

    • O atoms in rare gas matrices

    • PAH Molecules in Rare Gas Matrices

    • Anthracene-9,10-Endoperoxide and its Derivatives in Rare Gas Matrices

  • Photophysics of the PAH/O2 CCs in Ar Matrices

    • Laser Photolysis of APO and DMAPO in Ar Matrices

    • Lifetimes of Singlet Oxygen in the CCs

  • Laser Photolysis of Singlet Oxygen in the PAH/O2 CCs in Ar Matrices

  • Conclusions and Future Perspectives

    • Implications to Laboratory Photochemistry

    • Implications to Atmospheric Chemistry

  • References