Chapter 4. Transition-Metal Ion Chemistry of Peroxides in the Gas Phase

  1. Waldemar Adam
  1. Detlef Schröder,
  2. Christoph A. Schalley and
  3. Helmut Schwarz

Published Online: 30 JUN 2005

DOI: 10.1002/3527600396.ch30

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

How to Cite

Schröder, D., Schalley, C. A. and Schwarz, H. (2000) Transition-Metal Ion Chemistry of Peroxides in the Gas Phase , in Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer (ed W. Adam), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527600396.ch30

Editor Information

  1. Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

Author Information

  1. Institut für Organische Chemie, Technischen Universität Berlin, Strasse des 17. Juni 135, D-10623 Berlin, Germany

Publication History

  1. Published Online: 30 JUN 2005
  2. Published Print: 11 SEP 2000

ISBN Information

Print ISBN: 9783527271504

Online ISBN: 9783527600397

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Keywords:

  • transition-metal chemistry;
  • peroxides;
  • reactive metal-oxo species;
  • alkyl hydroperoxides;
  • dialkyl peroxides;
  • transition-metal cations;
  • metal peroxides;
  • O2-activation

Summary

This chapter contains sections titled:

  • Introduction

  • Peroxides for the Generation of Reactive Metal-Oxo Species

    • Potential-energy Surfaces of [Fe,H2,O2]+ and [Fe,H2,O2]2+

  • Metal-Ion Chemistry of Organic Peroxides

    • Reactions of Alkyl Hydroperoxides with Transition-Metal Cations

    • Reactions of Dialkyl Peroxides with Transition-Metal Cations

  • Metal Peroxides

    • [M]OOR+ Ions

    • The [M,O2] Manifold

    • Peroxo Units in Metal Clusters

  • O2-Activation and Peroxides

    • The Spin Problem

    • The Stoichiometry/Selectivity Problem

    • Possible Solutions

  • Performance of the Research Project

  • Spin-off

  • References