Chapter 3. Preparative Use of Peroxidic Oxidants for Oxygen-Transfer Reactions

  1. Waldemar Adam
  1. Waldemar Adam,
  2. Hans-Georg Degen,
  3. Aurelia Pastor,
  4. Chantu R. Saha-Möller,
  5. Simon B. Schambony and
  6. Cong-Gui Zhao

Published Online: 30 JUN 2005

DOI: 10.1002/3527600396.ch4

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

How to Cite

Adam, W., Degen, H.-G., Pastor, A., Saha-Möller, C. R., Schambony, S. B. and Zhao, C.-G. (2000) Preparative Use of Peroxidic Oxidants for Oxygen-Transfer Reactions, in Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer (ed W. Adam), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527600396.ch4

Editor Information

  1. Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

Author Information

  1. Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

Publication History

  1. Published Online: 30 JUN 2005
  2. Published Print: 11 SEP 2000

ISBN Information

Print ISBN: 9783527271504

Online ISBN: 9783527600397

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Keywords:

  • oxygen-transfer reactions;
  • Schenck Ene reactions;
  • regioselectivity;
  • diastereoselectivity;
  • cycloaddition;
  • dioxiranes;
  • S heteroatoms;
  • N heteroatoms;
  • asymmetric oxidations

Summary

This chapter contains sections titled:

  • Background and Objectives

  • Oxygen-Transfer Reactions with Singlet Oxygen

    • Regio- and Diastereoselective Schenck Ene Reactions

      • Regioselectivity

      • Diastereoselectivity

    • Diastereoselective [4+2] and [2+2] Cycloadditions of Singlet Oxygen

      • [4+2] Cycloaddition

      • [2+2] Cycloaddition

  • Oxygen-Transfer Reactions with Dioxiranes

    • Oxidation of π Bonds

      • Epoxidations

      • Arene Oxidation

      • Nitronate-Anion Oxidation

    • Oxidation of S and N Heteroatoms

    • Oxidation of σ Bonds

      • C[BOND]H Oxidation

      • Si[BOND]H Oxidation

    • Asymmetric Oxidations with Dioxiranes

  • Oxygen-Transfer Reactions with Perhydrates

  • References