Chapter 6. Carbonyl O-Oxides and Dioxiranes – From Laboratory Curiosities to Useful Reagents

  1. Waldemar Adam
  1. K. Block,
  2. W. Kappert,
  3. A. Kirschfeld,
  4. S. Muthusamy,
  5. K. Schroeder,
  6. W. Sander,
  7. E. Kraka,
  8. C. Sosa and
  9. D. Cremer

Published Online: 30 JUN 2005

DOI: 10.1002/3527600396.ch7

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer

How to Cite

Block, K., Kappert, W., Kirschfeld, A., Muthusamy, S., Schroeder, K., Sander, W., Kraka, E., Sosa, C. and Cremer, D. (2000) Carbonyl O-Oxides and Dioxiranes – From Laboratory Curiosities to Useful Reagents, in Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer (ed W. Adam), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527600396.ch7

Editor Information

  1. Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

Author Information

  1. Lehrstuhl für Organische Chemie II, Ruhr-Universität, D-44780 Bochum, Germany

Publication History

  1. Published Online: 30 JUN 2005
  2. Published Print: 11 SEP 2000

ISBN Information

Print ISBN: 9783527271504

Online ISBN: 9783527600397

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Keywords:

  • dimesitylketone O-oxide;
  • dimesityldioxirane;
  • synthesis;
  • spectroscopic characterization;
  • thermal decay;
  • reactivity

Summary

This chapter contains sections titled:

  • Introduction

  • Dimesitylketone O-oxide

    • Synthesis

    • Spectroscopic Characterization

    • Thermal Decay

  • Dimesityldioxirane

    • Synthesis and Structural Characterization

    • Reactivity

  • Other Stable Carbonyl Oxides and Dioxiranes

  • Conclusion

  • References