Chapter 6. High-Spin Metal-Ion-Containing Molecules

  1. Prof. Dr. Joel S. Miller2 and
  2. Prof. Dr. Marc Drillon3
  1. Talal Mallah and
  2. Arnaud Marvilliers

Published Online: 30 JAN 2003

DOI: 10.1002/3527600590.ch6

Magnetism: Molecules to Materials II: Models and Experiments

Magnetism: Molecules to Materials II: Models and Experiments

How to Cite

Mallah, T. and Marvilliers, A. (2003) High-Spin Metal-Ion-Containing Molecules, in Magnetism: Molecules to Materials II: Models and Experiments (eds J. S. Miller and M. Drillon), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527600590.ch6

Editor Information

  1. 2

    University of Utah, 315 S. 1400 E. RM Dock, Salt Lake City, UT 84112-0850, USA

  2. 3

    CNRS, Inst. de Physique et Chimie des Matériaux de Strasbourg, 23 Rue du Loess, 67037 Strasbourg Cedex, France

Author Information

  1. Laboratoire de Chimie Inorganique, UMR CNRS 8613, Université Paris-Sud, 91405 Orsay, France

Publication History

  1. Published Online: 30 JAN 2003
  2. Published Print: 12 JUL 2001

ISBN Information

Print ISBN: 9783527303014

Online ISBN: 9783527600595

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Keywords:

  • high-spin;
  • spin frustration;
  • carboxylate;
  • hydroxypyridonate;
  • host-guest approach;
  • hexanuclear iron(III) rings;
  • hexanuclear manganese rings;
  • spin ground state;
  • antiferromagneti;
  • ferromagnetic;
  • paramagnetic species

Summary

This chapter contains sections titled:

  • Introduction

  • Self-assembly of Molecular Clusters

    • Competing Interactions and Spin Frustration

    • The Carboxylate Family

    • The Hydroxypyridonate Family

  • Host-Guest Approach

    • Hexanuclear Iron(III) Rings

    • Hexanuclear Manganese Rings

  • Step-by-step Rationale Approach

    • Complex as Ligand and Complex as Metal

    • Predicting the Spin Ground State

    • Antiferromagnetic Approach

    • Ferromagnetic Approach

    • Role of the Organic Ligand

    • Molecules with Two Shells of Paramagnetic Species

  • Conclusion