Chapter 5. Determination of Potential Energy Curve in Different Regions of Internuclear Separation

  1. Dr. Jarosław Koperski

Published Online: 15 MAY 2003

DOI: 10.1002/3527600817.ch5

Van der Waals Complexes in Supersonic Beams

Van der Waals Complexes in Supersonic Beams

How to Cite

Koperski, J. (2002) Determination of Potential Energy Curve in Different Regions of Internuclear Separation, in Van der Waals Complexes in Supersonic Beams, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527600817.ch5

Author Information

  1. Instytut Fizyki im. M. Smoluchowiskiego, Uniwersytet Jagielloński, ul. Reymonta 4, 30-059 Kraków, Poland

Publication History

  1. Published Online: 15 MAY 2003
  2. Published Print: 9 DEC 2002

ISBN Information

Print ISBN: 9783527403844

Online ISBN: 9783527600816

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Keywords:

  • potential energy curve;
  • internuclear separation;
  • analysis;
  • excitation spectra;
  • Birge-Sponer method;
  • limiting near-dissociation expansions;
  • generalized near-dissociation expansions;
  • simulation of bound-bound vibrational spectra;
  • simulation of rotational structures;
  • analysis of fluorescence spectra;
  • modelling of bound-bound discrete transitions;
  • modelling of bound-free continuous spectra;
  • approximations for neutral-neutral long-range characteristics;
  • Kramer-Herschbach combination rule;
  • London-Drude theory;
  • Slater-Kirkwood formula;
  • internuclear separation approximations;
  • Liuti-Pirani method;
  • Le Roy radius evaluation

Summary

This chapter contains sections titled:

  • Analysis of excitation spectra

    • Birge-Sponer method

    • Limiting and generalized near-dissociation expansions

    • Simulation of bound-bound vibrational spectra

    • Simulation of rotational structures

  • Analysis of fluorescence spectra

    • Modelling of bound-bound discrete transitions and bound-free continuous spectra

  • Complementary results of excitation- and fluorescence-spectra simulations

  • Approximations for neutral-neutral long-range characteristics

    • Kramer-Herschbach combination rule

    • London-Drude theory of dispersion interaction

    • Slater-Kirkwood formula

  • Approximations for internuclear separation

    • Liuti-Pirani method

    • Le Roy radius evaluation