Chapter 11. Arenetricarbonylchromium Complexes: Ipso, Cine, Tele Nucleophilic Aromatic Substitutions

  1. Prof. Didier Astruc
  1. Françoise Rose-Munch and
  2. Eric Rose

Published Online: 23 FEB 2004

DOI: 10.1002/3527601767.ch11

Modern Arene Chemistry

Modern Arene Chemistry

How to Cite

Rose-Munch, F. and Rose, E. (2002) Arenetricarbonylchromium Complexes: Ipso, Cine, Tele Nucleophilic Aromatic Substitutions, in Modern Arene Chemistry (ed D. Astruc), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527601767.ch11

Editor Information

  1. Laboratoire de Chimie Organique et Organométallique, UMR CNRS No 5802, Université Bordeaux I, 33405 Talence Cedex, France

Author Information

  1. Laboratoire de Synthèse Organique et, Organométallique, UMR CNRS 7611, Université Pierre et Marie Curie, Boite Postale 181, Tour 44 - 1er étage, 4, Place Jussieu, F-75252 Paris Cedex 05, France

Publication History

  1. Published Online: 23 FEB 2004
  2. Published Print: 1 OCT 2002

ISBN Information

Print ISBN: 9783527304899

Online ISBN: 9783527601769

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Keywords:

  • arenetricarbonylchromium complexes;
  • nucleophilic aromatic substitutions;
  • arene reactivity;
  • bond formation

Summary

This chapter contains sections titled:

  • Introduction

    • Effects on Arene Reactivity of Cr(CO)3 Coordination

    • Coverage and Definitions

  • Ipso Nucleophilic Aromatic Substitutions

    • Carbon–Oxygen, –Sulfur and –Selenium Bond Formation

    • Carbon–Nitrogen and Carbon–Phosphorus Bond Formation

    • Carbon–Carbon Bond Formation

    • Carbon–Hydrogen and Carbon–Metal Bond Formation

  • Cine and Tele Nucleophilic Aromatic Substitutions

    • Cleavage of CaF and CaCl Bonds

    • Cleavage of CaO Bonds

    • Cleavage of CaN Bonds

  • Concluding Remarks