Chapter 7. Kinetics of Reactions on Surfaces

  1. Prof. Dr. I. Chorkendorff1 and
  2. Prof. Dr. J. W. Niemantsverdriet2

Published Online: 28 JAN 2005

DOI: 10.1002/3527602658.ch7

Concepts of Modern Catalysis and Kinetics

Concepts of Modern Catalysis and Kinetics

How to Cite

Chorkendorff, I. and Niemantsverdriet, J. W. (2003) Kinetics of Reactions on Surfaces, in Concepts of Modern Catalysis and Kinetics, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527602658.ch7

Author Information

  1. 1

    Technical University of Denmark, Interdisciplinary Research Center for Catalysis (ICAT), Building 312, DK 2800 Lyngby, Denmark

  2. 2

    Eindhoven University of Technology, Schuit Institute of Catalysis, NL 5600 MB Eindhoven, The Netherlands

Publication History

  1. Published Online: 28 JAN 2005
  2. Published Print: 8 OCT 2003

ISBN Information

Print ISBN: 9783527305742

Online ISBN: 9783527602650

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Keywords:

  • kinetics of reactions on surfaces;
  • surface reactions;
  • adsorption;
  • sticking;
  • sticking coefficients;
  • desorption;
  • lateral interactions in surface reactions;
  • dissociation reactions on surfaces;
  • intermediates in surface reactions;
  • association reactions;
  • Langmuir–Hinshelwood model;
  • micro-kinetic modeling;
  • reaction scheme;
  • rate expressions;
  • activation energy;
  • reaction orders;
  • ammonia synthesis catalyst

Summary

  • Elementary Surface Reactions

    • Adsorption and Sticking

      • Determination of Sticking Coefficients

    • Desorption

      • Quantitative Interpretation of TPD Data

      • Compensation Effect in Temperature Programmed Desorption

    • Lateral Interactions in Surface Reactions

    • Dissociation Reactions on Surfaces

    • Intermediates in Surface Reactions

    • Association Reactions

  • Kinetic Parameters from Fitting Langmuir–Hinshelwood Models

  • Micro-kinetic Modeling

    • Reaction Scheme and Rate Expressions

    • Activation Energy and Reaction Orders

    • Ammonia Synthesis Catalyst under Working Conditions